Change search
ReferencesLink to record
Permanent link

Direct link
Layered 2D alkyldiammonium lead iodide perovskites: synthesis, characterization, and use in solar cells
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry. SP Process Development, Sweden.ORCID iD: 0000-0003-2410-7366
Show others and affiliations
2016 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 4, no 40, 15638-15646 p.Article in journal (Refereed) Published
Abstract [en]

The synthetic route and properties of three 2D hybrid organic/inorganic lead iodide perovskite materials are reported. The 2D perovskites were synthesized from the reaction between PbI2 and the di-cations of 1,4-diaminobutane, 1,6-diaminohexane, and 1,8-diaminooctane. The resulting products were [NH3(CH2)(4)NH3] PbI4 (BdAPbI(4)), [NH3(CH2)(6)NH3]PbI4 (HdAPbI(4)), and [NH3(CH2)(8)NH3]PbI4 (OdAPbI(4)). Structural characterization shows that two dimensional perovskite structures were formed with inorganic structural planes separated by organic layers. Absorption spectra show band gaps of 2.37 eV (BdAPbI(4)), 2.44 eV (HdAPbI(4)), and 2.55 eV (OdAPbI(4)). The 2D perovskite materials were investigated as light absorbing materials in solid state solar cells. The best performing material under moist, ambient conditions was BdAPbI4 (1.08% efficiency), which was comparable to methylammonium Pb(II) iodide (MAPbI(3)) solar cells (2.1% efficiency) manufactured and studied under analogous conditions. When compared to MAPbI(3), the 2D materials have larger band gaps and lower photoconductivity, while BdAPbI(4) based solar cells shows a comparable absorbed photon-to-current efficiency as compared to MAPbI(3) based ones.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2016. Vol. 4, no 40, 15638-15646 p.
Keyword [en]
Organometal Halide Perovskites, Organic-Inorganic Perovskites, Optical-Properties, Phase-Transitions, Crystallization, Methylammonium, Semiconductors, Deposition, Transport, Absorber
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-196654DOI: 10.1039/c6ta05055gISI: 000386310600043ScopusID: 2-s2.0-84992699231OAI: oai:DiVA.org:kth-196654DiVA: diva2:1047674
Funder
StandUpSwedish Energy AgencySwedish Research CouncilKnut and Alice Wallenberg Foundation
Note

QC 20161118

Available from: 2016-11-18 Created: 2016-11-17 Last updated: 2017-01-23Bibliographically approved
In thesis
1.
The record could not be found. The reason may be that the record is no longer available or you may have typed in a wrong id in the address field.

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Safdari, MajidSvensson, Per H.Kloo, LarsGardner, James M.
By organisation
Applied Physical Chemistry
In the same journal
Journal of Materials Chemistry A
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 9 hits
ReferencesLink to record
Permanent link

Direct link