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Improving Estimates of the Crystallization Driving Force: Investigation into the Dependence on Temperature and Composition of Activity Coefficients in Solution
University of Limerick, Ireland.
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology. University of Limerick, Ireland.ORCID iD: 0000-0002-6647-3308
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology. University of Limerick, Ireland.
2016 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 16, no 12, 6951-6960 p.Article in journal (Refereed) Published
Abstract [en]

The influence of temperature and composition on solution activity coefficients has been investigated. Under most conditions, the temperature dependence of the activity coefficient is much weaker than the composition dependence. A novel and more accurate approach to estimate crystallization driving forces is proposed, where, rather than neglecting the activity coefficient ratio, it can be estimated from solid−liquid equilibrium data.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2016. Vol. 16, no 12, 6951-6960 p.
Keyword [en]
activity coefficient, thermodynamics, solubility
National Category
Other Chemical Engineering Physical Chemistry
Research subject
Chemical Engineering; Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-198541DOI: 10.1021/acs.cgd.6b01137OAI: oai:DiVA.org:kth-198541DiVA: diva2:1057385
Note

QC 20161219

Available from: 2016-12-17 Created: 2016-12-17 Last updated: 2016-12-19Bibliographically approved

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Svärd, MichaelRasmuson, Åke C.
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