Improving Estimates of the Crystallization Driving Force: Investigation into the Dependence on Temperature and Composition of Activity Coefficients in Solution
2016 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 16, no 12, 6951-6960 p.Article in journal (Refereed) Published
The influence of temperature and composition on solution activity coefficients has been investigated. Under most conditions, the temperature dependence of the activity coefficient is much weaker than the composition dependence. A novel and more accurate approach to estimate crystallization driving forces is proposed, where, rather than neglecting the activity coefficient ratio, it can be estimated from solid−liquid equilibrium data.
Place, publisher, year, edition, pages
American Chemical Society (ACS), 2016. Vol. 16, no 12, 6951-6960 p.
activity coefficient, thermodynamics, solubility
Other Chemical Engineering Physical Chemistry
Research subject Chemical Engineering; Chemistry
IdentifiersURN: urn:nbn:se:kth:diva-198541DOI: 10.1021/acs.cgd.6b01137OAI: oai:DiVA.org:kth-198541DiVA: diva2:1057385
QC 201612192016-12-172016-12-172016-12-19Bibliographically approved