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Calculations of circular intensity differences in electric-field-induced second harmonic generation
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1998 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 288, no 2-4, 371-376 p.Article in journal (Refereed) Published
Abstract [en]

Ab initio calculations of electric-field induced second-harmonic generation for chiral molecules are presented. The calculations employ cubic response theory and take into account electric-dipole, electric-quadrupole and magnetic-dipole interactions, which result in an intensity dependence on the helicity of the light. The circular intensity difference is calculated for the chiral molecules twisted ethylene, trans-1,2-dimethylcyclopropane and methyloxirane. The calculated circular intensity differences are small - being of the order of 10-4-10-3 - but such electric-field induced second harmonic generation intensity dependencies should be experimentally detectable.

Place, publisher, year, edition, pages
1998. Vol. 288, no 2-4, 371-376 p.
National Category
Theoretical Chemistry
URN: urn:nbn:se:kth:diva-198834ScopusID: 2-s2.0-0032557320OAI: diva2:1058703

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Available from: 2016-12-21 Created: 2016-12-21 Last updated: 2017-01-12Bibliographically approved

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