The A and B terms of magnetic circular dichroism revisited
2008 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 112, no 40, 9615-9618 p.Article in journal, Letter (Refereed) Published
The temperature-independent part of the magnetic circular dichroism spectrum is conventionally divided into the Faraday A and B terms, where the A term is nonzero only for systems with degenerate states. We propose that this separation is abandoned in favor of a unified temperature-independent term. This proposal is based on complex polarization propagator calculations on three structurally similar porphyrins. These calculations also suggest that the Soret band of Zn-porphyrin is determined by an isolated degenerate 2Eu state.
Place, publisher, year, edition, pages
American Chemical Society (ACS), 2008. Vol. 112, no 40, 9615-9618 p.
Optical properties, Porphyrins, Separation, Spectrum analysis, Zinc, Complex polarization propagators, Magnetic circular dichroism spectrum, Magnetic circular dichroisms, Soret bands, Dichroism
IdentifiersURN: urn:nbn:se:kth:diva-198766DOI: 10.1021/jp803135xISI: 000259760300001ScopusID: 2-s2.0-54849426682OAI: oai:DiVA.org:kth-198766DiVA: diva2:1059039
QC 201612222016-12-222016-12-212016-12-22Bibliographically approved