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Excitation and emission properties of platinum(II) acetylides at high and low concentrations
Linköping University, Sweden.ORCID iD: 0000-0002-1191-4954
2009 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 113, no 42, 11242-11249 p.Article in journal (Refereed) Published
Abstract [en]

Photophysical properties of platinum(II) acetylides in tetrahydrofuran (THF) solutions and incorporated in poly (methyl methacrylate) (PMMA) glasses have been studied over a large concentration range from 10 /ÀM to 50 mM. In general, the luminescence properties of the studied chromophores in the liquid state were also maintained in the solid state, except for shorter decay times of 50-90 μs of the triplet state in the glass compared with 200-300 μs in solution at low concentrations. The phosphorescence line shapes were found to be independent of both the chromophore concentration and the environment (THF and PMMA). The triplet state lifetimes did not change with concentration in the solid-state case, whereas, in solution, the decay becomes shorter at increasing concentration. The latter effect could be modeled with an additional linear quenching rate, kq in the range of (1 to 7) × 107 M-1 s-1. Excitation spectra of the triplet state at high concentrations, in both solutions and solid glasses, showed additional excitation bands on the long wavelength side compared with the corresponding measurements at low concentrations. This indicates enhanced singlet-triplet coupling due to intermolecular electronic interactions that become important at concentrations of 0.1 to 1 mM and above.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2009. Vol. 113, no 42, 11242-11249 p.
Keyword [en]
Acetylides, Chromophore concentrations, Concentration ranges, Decay time, Electronic interactions, Emission properties, Excitation bands, Excitation spectrum, High concentration, Line shape, Liquid state, Long wavelength, Low concentrations, Luminescence properties, Photophysical properties, Quenching rate, Singlet-triplet, Tetrahydrofurans, Triplet state, Triplet state lifetime, Chromophores, Esters, Glass, Luminescence, Platinum, Quenching, Concentration (process)
National Category
Theoretical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-198759DOI: 10.1021/jp905437cISI: 000270670700020PubMedID: 19827853Scopus ID: 2-s2.0-70350147597OAI: oai:DiVA.org:kth-198759DiVA: diva2:1059044
Funder
Swedish Research Council, 621-2007-5269
Note

QC 20160118

Available from: 2016-12-22 Created: 2016-12-21 Last updated: 2017-01-18Bibliographically approved

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