Change search
ReferencesLink to record
Permanent link

Direct link
Use of two-dimensional photoelectron spectroscopy in the decomposition of an inner-shell excitation spectrum broadened by super-Coster-Kronig decay
Show others and affiliations
2013 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 88, no 6, 062502Article in journal (Refereed) Published
Abstract [en]

The Ge 3p core excitation spectrum of the n-butylgermane molecule only reveals two peaks, whereas the rest of the fine structure is obscured due to the large lifetime broadenings of core-excited states. A two-dimensional presentation of resonant photoemission spectra allows us to observe some other resonances. The interpretation of experimental results is supported by ab initio calculations conducted at the four-component relativistic level of theory with full account made for spin-orbit interactions already in the zeroth-order Hamiltonian. © 2013 American Physical Society.

Place, publisher, year, edition, pages
2013. Vol. 88, no 6, 062502
Keyword [en]
Ab initio calculations, Core excitation, Core-excited state, Fine structures, Inner shell excitation, Resonant photoemission, Spin orbit interactions, Two-dimensional photoelectron spectroscopy, Germanium, Hamiltonians, Nuclear physics, Photoelectron spectroscopy, Two dimensional, Excited states
National Category
Theoretical Chemistry
URN: urn:nbn:se:kth:diva-198731DOI: 10.1103/PhysRevA.88.062502ScopusID: 2-s2.0-84890333812OAI: diva2:1059100

References: Glans, P., Lavilla, R.E., Ohno, M., Svensson, S., Bray, G., Wassdahl, N., Nordgren, J., (1993) Phys. Rev. A, 47, p. 1539. , PLRAAN 1050-2947 10.1103/PhysRevA.47.1539; Jurvansuu, M., Kivimäki, A., Aksela, S., (2001) Phys. Rev. A, 64, p. 012502. , PLRAAN 1050-2947 10.1103/PhysRevA.64.012502; King, G.C., Tronc, M., Read, F.H., Bradford, R.C., (1977) J. Phys. B, 10, p. 2479. , JPAMA4 0022-3700 10.1088/0022-3700/10/12/026; Sankari, R., Kivimäki, A., Huttula, M., Matila, T., Aksela, H., Aksela, S., Coreno, M., Prince, K.C., (2002) Phys. Rev. A, 65, p. 042702. , PLRAAN 1050-2947 10.1103/PhysRevA.65.042702; Kivimäki, A., Naves De Brito, A., Aksela, S., Aksela, H., Sairanen, O.-P., Ausmees, A., Osborne, S.J., Svensson, S., (1993) Phys. Rev. Lett., 71, p. 4307. , PRLTAO 0031-9007 10.1103/PhysRevLett.71.4307; Anin, D., Jänkälä, K., Huttula, S.-M., Huttula, M., (2012) Phys. Rev. A, 86, p. 063410. , PLRAAN 1050-2947 10.1103/PhysRevA.86.063410; Maracci, F., Platania, R., De, A.C., Souza, A.E., De Souza, G.G.B., (1989) Chem. Phys., 133, p. 291. , CMPHC2 0301-0104 10.1016/0301-0104(89)80209-5; Kivimäki, A., Aksela, H., Aksela, S., Sairanen, O.-P., (1993) Phys. Rev. B, 47, p. 4181. , PRBMDO 1098-0121 10.1103/PhysRevB.47.4181; Yang, H.-J., Tuan, H.-Y., (2012) J. Mater. Chem., 22, p. 2215. , JMACEP 0959-9428 10.1039/c1jm14875c; Sokell, E., Wills, A.A., Ćubric, D., Currell, F.J., Comer, J., Hammond, P., (1998) J. Electron Spectrosc. Relat. Phenom., 94, p. 107. , JESRAW 0368-2048 10.1016/S0368-2048(98)00145-5; Odling-Smee, M.K., Sokell, E., Wills, A.A., Hammond, P., (1999) J. Phys. B, 32, p. 2529. , JPAPEH 0953-4075 10.1088/0953-4075/32/11/305; Kukk, E., Wills, A., Berrah, N., Langer, B., Bozek, J.D., Nayadin, O., Alsherhi, M., Cubaynes, D., (1998) Phys. Rev. A, 57, p. 1485. , PLRAAN 1050-2947 10.1103/PhysRevA.57.R1485; Sokell, E., Wills, A.A., Wiedenhoeft, M., Feng, X., Rolles, D., Berrah, N., (2005) J. Phys. B, 38, p. 1535. , JPAPEH 0953-4075 10.1088/0953-4075/38/10/011; Kanter, E.P., (2011) Phys. Rev. Lett., 107, p. 233001. , PRLTAO 0031-9007 10.1103/PhysRevLett.107.233001; Verweyen, A., Wernet, Ph., Glatzel, P., Sonntag, B., Gerth, Ch., Godehusen, K., Zimmermann, P., (2000) J. Phys. B, 33, p. 1563. , JPAPEH 0953-4075 10.1088/0953-4075/33/8/307; Wang, H., Fink, R.F., Piancastelli, M.N., (2001) J. Phys. B, 34, p. 4417. , JPAPEH 0953-4075 10.1088/0953-4075/34/22/311; Prince, K.C., (1998) J. Synchrotron Radiat., 5, p. 565. , JSYRES 0909-0495 10.1107/S090904959800065X; Mårtensson, N., Baltzer, P., Brühwiler, P.A., Forsell, J.-O., Nilsson, A., Stenborg, A., Wannberg, B., (1994) J. Electron Spectrosc. Relat. Phenom., 70, p. 117. , JESRAW 0368-2048 10.1016/0368-2048(94)02224-N; Kivimäki, A., Pfeiffer, L., Aksela, H., Nõmmiste, E., Aksela, S., (1999) J. Electron Spectrosc. Relat. Phenom., p. 43. , JESRAW 0368-2048 10.1016/S0368-2048(98)00470-8; Aa. Jensen, H.J., Bast, R., Saue, T., Visscher, L., Bakken, V., Dyall, K.G., Dubillard, S., Yamamoto, S., (2012),, DIRAC, a relativistic ab initio electronic structure program, Release DIRAC12 (, with contributions from (seeEkström, U., Norman, P., Carravetta, V., (2006) Phys. Rev. A, 73, p. 022501. , PLRAAN 1050-2947 10.1103/PhysRevA.73.022501; Villaume, S., Ekström, U., Ottosson, H., Norman, P., (2010) Phys. Chem. Chem. Phys., 12, p. 5596. , PPCPFQ 1463-9076 10.1039/b926109e; Ekström, U., Ottosson, H., Norman, P., (2007) J. Phys. Chem. C, 111, p. 13846. , 1932-7447 10.1021/jp0717084; Becke, A.D., (1993) J. Chem. Phys., 98, p. 5648. , JCPSA6 0021-9606 10.1063/1.464913; Dunning, Jr.T.H., (1989) J. Chem. Phys., 90, p. 1007. , JCPSA6 0021-9606 10.1063/1.456153; Henriksson, J., Ekström, U., Norman, P., (2006) J. Chem. Phys., 124, p. 214311. , JCPSA6 0021-9606 10.1063/1.2204604; McGilp, J.F., Weightman, P., (1976) J. Phys. C: Solid State Phys., 9, p. 3541. , JPSOAW 0022-3719 10.1088/0022-3719/9/18/021

Available from: 2016-12-22 Created: 2016-12-21 Last updated: 2016-12-22

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Norman, P.
In the same journal
Physical Review A. Atomic, Molecular, and Optical Physics
Theoretical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 2 hits
ReferencesLink to record
Permanent link

Direct link