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Use of two-dimensional photoelectron spectroscopy in the decomposition of an inner-shell excitation spectrum broadened by super-Coster-Kronig decay
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2013 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 88, no 6, 062502Article in journal (Refereed) Published
Abstract [en]

The Ge 3p core excitation spectrum of the n-butylgermane molecule only reveals two peaks, whereas the rest of the fine structure is obscured due to the large lifetime broadenings of core-excited states. A two-dimensional presentation of resonant photoemission spectra allows us to observe some other resonances. The interpretation of experimental results is supported by ab initio calculations conducted at the four-component relativistic level of theory with full account made for spin-orbit interactions already in the zeroth-order Hamiltonian. © 2013 American Physical Society.

Place, publisher, year, edition, pages
2013. Vol. 88, no 6, 062502
Keyword [en]
Ab initio calculations, Core excitation, Core-excited state, Fine structures, Inner shell excitation, Resonant photoemission, Spin orbit interactions, Two-dimensional photoelectron spectroscopy, Germanium, Hamiltonians, Nuclear physics, Photoelectron spectroscopy, Two dimensional, Excited states
National Category
Theoretical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-198731DOI: 10.1103/PhysRevA.88.062502ScopusID: 2-s2.0-84890333812OAI: oai:DiVA.org:kth-198731DiVA: diva2:1059100
Note

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