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Tuning for Visible Fluorescence and Near-Infrared Phosphorescence on a Unimolecular Mechanically Sensitive Platform via Adjustable CH-pi Interaction
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology. (Prof. Yi Luo)ORCID iD: 0000-0001-6508-8355
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2017 (English)In: ACS Applied Materials and Interfaces, ISSN 1944-8244, E-ISSN 1944-8252, Vol. 9, no 4, 3865-3872 p.Article in journal (Refereed) Published
Abstract [en]

CH-pi interaction-assisted alignment of organic conjugated systems has played an important role to regulate molecular electronic and photophysical properties, whereas harnessing such a smart noncovalent interaction into the tuning of unimolecular complex emissive bands covering a wide spectral region remains a challenging research topic. Since the tuning for visible and near-infrared emissive properties in a single pi-functional platform relates to its multicolor luminescent behaviors and potential superior application in analysis, bioimaging, and sensing, herein, we report a proportional control of the singlet and triplet emissions that cover visible and near-infrared spectral regions, respectively, can be straightforwardly achieved by CH-pi interaction-assisted self-assembly at the unimolecular level. Employing an octathionaphthalene-based single luminophore as a prototype, we find that a strength-adjustable CH-pi interaction-assisted self-assembly can be established in mixed DMF/H2O and in the film state. The hybridization of planar local excited and intramolecular charge transfer transitions occurs on the basis, allowing a competitive inhibition to the intersystem crossing process to generate a complex emission composed of visible fluorescence and near-infrared phosphorescence. Furthermore, reversible mechanochromic and mechanoluminescent conversions of the corresponding solid sample can both be observed to rely on a corresponding self-assembly alternation. These results can probably provide new visions for the development of future intelligent and multifunctional luminescent materials.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2017. Vol. 9, no 4, 3865-3872 p.
Keyword [en]
CH-pi interaction, visible fluorescence and near-infrared phosphorescence, unimolecular complex emission, tunable intersystem crossing, mechanical stimuli
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-203156DOI: 10.1021/acsami.6b15939ISI: 000393355900071PubMedID: 28073247Scopus ID: 2-s2.0-85011649901OAI: oai:DiVA.org:kth-203156DiVA: diva2:1081974
Note

QC 20170315

Available from: 2017-03-15 Created: 2017-03-15 Last updated: 2017-06-09Bibliographically approved

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