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Phase equilibria for the oxygen-water system up to elevated temperatures and pressures
KTH, Superseded Departments, Chemical Engineering and Technology.
KTH, Superseded Departments, Chemical Engineering and Technology.
2004 (English)In: Fluid Phase Equilibria, ISSN 0378-3812, E-ISSN 1879-0224, Vol. 222-223, 39-47 p.Article in journal (Refereed) Published
Abstract [en]

A new thermodynamic model was presented to calculate the phase equilibria for the oxygen-water system. The modified Redlich-Kwong equation of state with a new correlated cross-interaction parameter was used to calculate fugacity coefficients for the vapor phase. The dissolved oxygen followed Henry's law. A new expression was correlated from the experimental data to calculate Henry's constant of oxygen. The calculated results of equilibrium composition were compared with the available experimental data and those calculated by other models with different parameters. The comparison revealed that the new model is suitable for calculating both liquid and vapor compositions while the empirical method is only suitable for estimating the liquid composition. Furthermore, compared to the model proposed by Rebenovich and Beketov, the calculated results of the vapor composition with the new model are better.

Place, publisher, year, edition, pages
2004. Vol. 222-223, 39-47 p.
Keyword [en]
oxygen, water, equation of state, vapor-liquid equilibrium, Henry's constant
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-6209DOI: 10.1016/j.fluid.2004.06.029ISI: 000223777100007Scopus ID: 2-s2.0-4344672952OAI: oai:DiVA.org:kth-6209DiVA: diva2:10854
Note
QC 20100902Available from: 2006-10-06 Created: 2006-10-06 Last updated: 2017-12-14Bibliographically approved
In thesis
1. Thermodynamic properties of humid air and their application in advanced power generation cycles
Open this publication in new window or tab >>Thermodynamic properties of humid air and their application in advanced power generation cycles
2006 (English)Doctoral thesis, comprehensive summary (Other scientific)
Abstract [en]

Water or steam is added into the working fluid (often air) in gas turbines to improve the performance of gas turbine cycles. A typical application is the humidified gas turbine that has the potential to give high efficiencies, high specific power output, low emissions and low specific investment. A heat recovery system is integrated in the cycle with a humidifier for moisturizing the high-pressure air from the compressor as a kernel. Based on today’s gas turbines, the operating temperature and pressure in the humidifier are up to about 523 K and 40 bar, respectively. The operating temperature of the heat exchanger after the humidifier is up to 1773 K. The technology of water or steam addition is also used in the process of compressed air energy storage (CAES), and the operating pressure is up to 150 bar.

Reliable thermodynamic properties of humid air are crucial for the process simulation and the traceable performance tests of turbomachinery and heat exchanger in the cycles. Several models have been proposed. However, the application range is limited to 400 K and 100 bar because of the limited experimental data for humid air. It is necessary to investigate the thermodynamic properties of humid air at elevated temperatures and pressures to fill in the knowledge gap.

In this thesis, a new model is proposed based on the modified Redlich-Kwong equation of state in which a new cross interaction parameter between molecular oxygen and water is obtained from the fitting of the experimental data of oxygen-water system. The liquid phase is assumed to follow Henry’s law to calculate the saturated composition.

The results of the new model are verified by the experimental data of nitrogen-water and oxygen-water systems from ambient temperature and pressure to 523 K and 200 bar, respectively. Properties of air-water system are predicted without any additional parameter and compared with the available experimental data to demonstrate the reliability of the new model for air-water system. The results of air-water system predicted using the new model are compared with those calculated using other real models. The comparison reveals that the new model has the same calculation accuracy as the best available model but can be used to a wider temperature and pressure range. The results of the new model are also compared with those of the ideal model and the ideal mixing model from ambient temperature and pressure to 1773 K and 200 bar to investigate the effect of the models on the thermodynamic properties of humid air.

To investigate the impact of thermodynamic properties on the simulation of systems and their components, different models (ideal model, ideal mixing model and two real models) are used to calculate the thermodynamic properties of humid air in the simulation of the compressor, humidification tower, and heat exchanger in a humidified gas turbine cycle. The simulation reveals that a careful selection of a thermodynamic property model is crucial for the cycle design. The simulation results provide a useful tool for predicting the performance of the system and designing the humidified cycle components and systems.

Place, publisher, year, edition, pages
Stockholm: KTH, 2006. 75 p.
Series
Trita-KET, ISSN 1104-3466 ; 229
Keyword
air-water mixture, humid air, properties, wet cycles, dry air, water, enthalpy, entropy, heat capacity, density, evaporative gas turbine, compressed air energy storage
National Category
Chemical Engineering
Identifiers
urn:nbn:se:kth:diva-4129 (URN)91-7178-437-3 (ISBN)
Public defence
2006-10-23, F3, KTH, Lindstedtsvägen 26, Stockholm, 13:30
Opponent
Supervisors
Note
QC 20100902Available from: 2006-10-06 Created: 2006-10-06 Last updated: 2010-09-02Bibliographically approved

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