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Tailoring Soft Polymer Networks Based on Sugars and Fatty Acids toward Pressure Sensitive Adhesive Applications
KTH, Superseded Departments, Fibre and Polymer Technology.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0001-7543-5322
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0002-5444-7276
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0003-3201-5138
2017 (English)In: ACS SUSTAINABLE CHEMISTRY & ENGINEERING, ISSN 2168-0485, Vol. 5, no 3, 2632-2638 p.Article in journal (Refereed) Published
Abstract [en]

The present work describes the synthesis and characterization of fully biobased soft polymer networks for pressure sensitive adhesives applications. The incorporation of different sugars into fatty-acid-based monomers, made it possible to tailor the viscoelastic properties of the materials. Lipase catalysis allowed to afford monomers with varying hydroxyl content and epoxy-functionalities. Step-growth polymerization catalyzed by DBU resulted in soft-polyester networks through combination of the monomers with a biobased diacid. Rheological and adhesion studies were performed to elucidate the different viscoelastic and adhesive properties of the materials as a function of their composition.

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2017. Vol. 5, no 3, 2632-2638 p.
Keyword [en]
Pressure sensitive adhesives, Soft polymer networks, Lipase catalysis, Fatty acids, Biobased, Vegetable oils, Sorbitol
National Category
Polymer Chemistry Polymer Technologies
Identifiers
URN: urn:nbn:se:kth:diva-205478DOI: 10.1021/acssuschemeng.6b02978ISI: 000395846900067Scopus ID: 2-s2.0-85014509029OAI: oai:DiVA.org:kth-205478DiVA: diva2:1094714
Note

QC 20170510

Available from: 2017-05-10 Created: 2017-05-10 Last updated: 2017-05-10Bibliographically approved

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CiteExportLink to record
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