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Formation of N-oxide in the third oxidation of [Ru-II(tpy)(L)(OH2)](2+)
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 41, 5622-5624 p.Article in journal (Refereed) Published
Abstract [en]

The widely studied water oxidation catalyst [Ru-II(tpy)(L)(OH2)](2+) (tpy = 2,2': 6',2"-terpyridine, L = bpy = 2,2'-bipyridine or L = bpm = 2,2'-bipyrimidine) is still under scrutiny. Here we present a new suggestion for one of the key steps, results that could resolve conflicting interpretations of experimental results. Instead of the previously proposed Ru-V=O species, a proposed key species in water oxidation catalysis, we propose that the third oxidation of RuII could lead to a Ru-III N-oxide, via rapid water coordination followed by oxidation and concerted N-O bond formation.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2017. Vol. 53, no 41, 5622-5624 p.
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Other Chemistry Topics
Identifiers
URN: urn:nbn:se:kth:diva-208806DOI: 10.1039/c7cc03041jISI: 000401638600008PubMedID: 28480458OAI: oai:DiVA.org:kth-208806DiVA: diva2:1109524
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Note

QC 20170614

Available from: 2017-06-14 Created: 2017-06-14 Last updated: 2017-06-14Bibliographically approved

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