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Phase equilibria study and thermodynamic description of the BaO-CaO-Al2O3 system
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering. Thermo-Calc Software AB, Sweden.ORCID iD: 0000-0002-8493-9802
2017 (English)In: Journal of The American Ceramic Society, ISSN 0002-7820, E-ISSN 1551-2916, Vol. 100, no 6, 2722-2731 p.Article in journal (Refereed) Published
Abstract [en]

A combined experimental investigation and thermodynamic assessment was performed for the BaO-CaO-Al2O3 system. By using a high-temperature equilibration/quenching technique and scanning electron microscopy, electron probe microanalysis, and X-ray powder diffraction analysis, the phase equilibria at 1500°C and phase stability of BaCa2Al8O15 phase were determined. An extensive literature survey was conducted for the experimental and thermodynamic modeling data of the BaO-CaO-Al2O3 system. According to the literature data and the present measurements, a thermodynamic assessment was made in order to obtain a set of self-consistent thermodynamic parameters to describe the BaO-CaO-Al2O3 system. Based on the thermodynamic parameters acquired in this work, isothermal sections at 1100°C, 1250°C, 1400°C, 1475°C, and 1500°C and the BaO·Al2O3-CaO·Al2O3 and BaO·6Al2O3-CaO·6Al2O3 joints were calculated and compared with the available experimental data.

Place, publisher, year, edition, pages
Blackwell Publishing, 2017. Vol. 100, no 6, 2722-2731 p.
Keyword [en]
glass-ceramics, phase equilibria, thermodynamics
National Category
Metallurgy and Metallic Materials
Identifiers
URN: urn:nbn:se:kth:diva-209599DOI: 10.1111/jace.14793ISI: 000402610900045Scopus ID: 2-s2.0-85019968258OAI: oai:DiVA.org:kth-209599DiVA: diva2:1113823
Note

QC 20170622

Available from: 2017-06-22 Created: 2017-06-22 Last updated: 2017-07-03Bibliographically approved

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CiteExportLink to record
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  • apa
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