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Csp(3)-H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.ORCID iD: 0000-0002-1553-4027
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2017 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 23, no 8, 1748-1751 p.Article in journal (Refereed) Published
Abstract [en]

Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C-H activation of 2-(dimethylamino) pyridine is not chelation assisted, which has not been described before for Csp(3)-H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino) pyridine was studied by DFT calculations and kinetic measurements.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2017. Vol. 23, no 8, 1748-1751 p.
Keyword [en]
cyclometallation, density functional calculations, iridium, pincer complexes, undirected C-H activation
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-205092DOI: 10.1002/chem.201604469ISI: 000395754800003PubMedID: 27982473OAI: oai:DiVA.org:kth-205092DiVA: diva2:1115065
Note

QC 20170626

Available from: 2017-06-26 Created: 2017-06-26 Last updated: 2017-06-26Bibliographically approved

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