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Crystal Growth of Salicylic Acid in Organic Solvents
University of Limerick, Ireland.
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Transport Phenomena. KTH Royal institute of technology.ORCID iD: 0000-0002-6647-3308
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Transport Phenomena. University of Limerick, Ireland.
2017 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 17, no 6, p. 2964-2974Article in journal (Refereed) Published
Abstract [en]

The crystal growth rate of salicylic acid has been determined by seeded isothermal desupersaturation experiments in different organic solvents (methanol, acetone, ethyl acetate, and acetonitrile) and at different temperatures (10, 15, 20, and 25 °C). In situ ATR-FTIR spectroscopy and principal component analysis (PCA) were employed for the determination of solution concentration. Activity coefficient ratios are approximately accounted for in the driving force determination. The results show that the dependence of the growth rate on the solvent at equal driving force varies with temperature; e.g., at 25 °C, the growth rate is highest in ethyl acetate and lowest in acetonitrile, while at 15 °C the growth rate is highest in acetonitrile. The growth rate data are further examined within the Burton Cabrera Franck (BCF) and the Birth and Spread (B+S) theories, and the results point to the importance of the surface diffusion step. Interfacial energies determined by fitting the B+S model to the growth rate data are well-correlated to interfacial energies previously determined from primary nucleation data.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2017. Vol. 17, no 6, p. 2964-2974
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-209882DOI: 10.1021/acs.cgd.6b01415ISI: 000403136200010Scopus ID: 2-s2.0-85020288873OAI: oai:DiVA.org:kth-209882DiVA, id: diva2:1115119
Note

QC 20170626

Available from: 2017-06-26 Created: 2017-06-26 Last updated: 2019-03-11Bibliographically approved

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