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An arylboronate locked fluorescent probe for hypochlorite
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.ORCID iD: 0000-0001-6508-8355
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2017 (English)In: The Analyst, ISSN 0003-2654, E-ISSN 1364-5528, Vol. 142, no 12, 2104-2108 p.Article in journal (Refereed) Published
Abstract [en]

An unusual arylboronate based fluorescent probe R1 was synthesized for the selective and sensitive detection of ClO-. A detailed mechanistic study revealed that R1 reacted with ClO- through an oxidation to chlorination mechanism, and the arylboronate moiety in R1 acted as a "lock" to eliminate the effects of pH fluctuations. With this design strategy, R1 was successfully used to detect as low as 6.4 nM of ClO- over other ROS species in a wide pH range from 4.5 to 9.0.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2017. Vol. 142, no 12, 2104-2108 p.
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Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-210345DOI: 10.1039/c7an00467bISI: 000403318300005OAI: oai:DiVA.org:kth-210345DiVA: diva2:1119535
Note

QC 20170704

Available from: 2017-07-04 Created: 2017-07-04 Last updated: 2017-07-04Bibliographically approved

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