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Determination of the vanadium solubility in the Al2O3-CaO(25mass%)-SiO2 system
Swerea MEFOS.ORCID iD: 0000-0002-7708-0809
Swerea MEFOS.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.ORCID iD: 0000-0002-3548-8638
2014 (English)In: Calphad, ISSN 0364-5916, E-ISSN 1873-2984, Vol. 47, p. 50-55Article in journal (Refereed) Published
Abstract [en]

Vanadium (V) solubility in the Al2O3-CaO(25mass%)-SiO2 system was determined experimentally at 1873K and at a fixed oxygen potential of 9.37•10-11 bar. EPMA microanalyses were employed to identify the phases and their compositions in the quenched samples. It showed that the solubility of V-oxide increased slightly with decreasing Al2O3-content in the interval from 3mass% to 53mass%. The maximum V-solubility was up to 7mass% (as V). A solid solution rich in V-oxide was detected. The Al2O3 solubility in this solid solution was found to increase with increasing Al2O3-content in the liquid.

Place, publisher, year, edition, pages
Elsevier, 2014. Vol. 47, p. 50-55
Keywords [en]
vanadium, solubility, V2O3, equilibrium, experimental
National Category
Metallurgy and Metallic Materials
Research subject
Chemical Engineering; Materials Science and Engineering
Identifiers
URN: urn:nbn:se:kth:diva-213738DOI: 10.1016/j.calphad.2014.06.003ISI: 000346224700005Scopus ID: 2-s2.0-84903976104OAI: oai:DiVA.org:kth-213738DiVA, id: diva2:1138657
Projects
MISTRA Stålkretsloppet delprojekt Vanadin
Funder
Mistra - The Swedish Foundation for Strategic Environmental Research, 88031
Note

QC 20170911

Available from: 2017-09-06 Created: 2017-09-06 Last updated: 2018-02-28Bibliographically approved

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Sichen, Du

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