Iodoargentates and Cuprates Stabilized by Sulphonium Cations with Long Alkyl Chains
2003 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 12, 2352-2355 p.Article in journal (Refereed) Published
[DodMe2S]22AgI3 and [DodMe2S] Ag2I3 were obtained from mixtures of dodecyldimethylsulfonium iodide and silver iodide in acetonitrile solution. [DodMe2S]2AgI3 crystallizes in the orthorhombic crystal system, space group Pbca and contains trigonal planar anions AgI32-, while [DodMe2S] Ag2I3 crystallizes in the triclinic crystal system, space group P1, and consists of polymeric anions 1∞(Ag2I3)-. In both structures, the sulfonium cations form a layer of parallel and interpenetrating dodecyl chains with the sulfoniumdimethyl groups on both sides of the layer. [DodMe2S]2CuI3 was obtained from dodecyldimethylsulfonium iodide and copper iodide mixtures and is isostructural with the corresponding silver compound.
Place, publisher, year, edition, pages
2003. no 12, 2352-2355 p.
Cations, Copper, Crystal structure, Iodide, Silver
IdentifiersURN: urn:nbn:se:kth:diva-6711DOI: 10.1002/ejic.200200667ISI: 000184022400019OAI: oai:DiVA.org:kth-6711DiVA: diva2:11498
QC 201009202005-09-222005-09-222010-10-13Bibliographically approved