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An experimental method to identify various oxygen species transported in oxides
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Corrosion Science.
2007 (English)In: Journal of Membrane Science, ISSN 0376-7388, E-ISSN 1873-3123, Vol. 306, no 1-2, 166-172 p.Article in journal (Refereed) Published
Abstract [en]

Oxygen transport in oxides can take place in molecular, atomic and ionic form. An experimental method is described which separates the contributions of molecules, atoms and ions to the overall oxygen transport in oxides. The method comprises gas phase analysis and the use of oxygen isotopes O-16 and O-18. In the general case, exposure to non-equilibrated O-2 containing 60-70% O-18 is optimal to obtain the highest accuracy in the measurement. The method is exemplified by distinguishing non-ionic (molecular and atomic) oxygen transport from ionic oxygen transport in a commercial yttria-stabilized zirconia (YSZ) sample in the temperature range of 600-900 degrees C. There is approximately 35% molecular, 20% atomic transport and 45% ionic oxygen transport in YSZ at 600 degrees C. It is found that the fraction percent of non-ionic oxygen transport decreases with increasing temperature, and ionic oxygen transport increases sharply with increasing temperature.

Place, publisher, year, edition, pages
Elsevier , 2007. Vol. 306, no 1-2, 166-172 p.
Keyword [en]
molecular oxygen transport, atomic oxygen transport, ionic oxygen transport, gas phase analysis, oxides
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-7054DOI: 10.1016/j.memsci.2007.08.039ISI: 000251722700017Scopus ID: 2-s2.0-35748964732OAI: oai:DiVA.org:kth-7054DiVA: diva2:11946
Note
QC 20111005Available from: 2007-05-08 Created: 2007-05-08 Last updated: 2017-12-14Bibliographically approved

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