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Divalent Pseudorotaxane with Polarized Plug-Socket and Padlock Functions
East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Theoretical Chemistry and Biology.ORCID iD: 0000-0001-6508-8355
East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China..
East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China.;East China Univ Sci & Technol, Sch Chem & Mol Engn, Feringa Nobel Prize Scientist Joint Res Ctr, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China..
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2018 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 20, no 6, p. 1487-1490Article in journal (Refereed) Published
Abstract [en]

A dual-pore structured host composed of one 24-crown-8 and one 34-crown-10, and a "U"-shaped guest consisting of two different recognition units, one dibenzylammonium and one viologen, were synthesized and bound 1:1 into a divalent pseudorotaxane P1. P1 can mimic the inserting and pulling out functions of a polarized plug-socket system under solvent driven stimulus and can also realize the locking and unlocking actions of a padlock under pH stimulus.

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2018. Vol. 20, no 6, p. 1487-1490
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Chemical Sciences
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URN: urn:nbn:se:kth:diva-225718DOI: 10.1021/acs.orglett.7b03867ISI: 000428003600003PubMedID: 29488384Scopus ID: 2-s2.0-85044078009OAI: oai:DiVA.org:kth-225718DiVA, id: diva2:1196739
Note

QC 20180411

Available from: 2018-04-11 Created: 2018-04-11 Last updated: 2018-04-11Bibliographically approved

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Li, Xin

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