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Microdroplet deposition under a liquid medium
KTH, School of Engineering Sciences (SCI), Centres, Linné Flow Center, FLOW.ORCID iD: 0000-0003-3132-7252
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Analytical Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Analytical Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Analytical Chemistry.
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2007 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 23, no 3, 1171-1177 p.Article in journal (Refereed) Published
Abstract [en]

An experimental and numerical study of the factors affecting the reproducibility of microdroplet depositions performed under a liquid medium is presented. In the deposition procedure, sample solution is dispensed from the end of a capillary by the aid of a pressure pulse onto a substrate with pillar-shaped sample anchors. The deposition was modeled using the convective Cahn-Hilliard equation coupled with the Navier-Stokes equations with added surface tension and gravity forces. To avoid a severe time-step restriction imposed by the fourth-order Cahn-Hilliard equation, a semi-implicit scheme was developed. An axisymmetric model was used, and an adaptive finite element method was implemented. In both the experimental and numerical study it was shown that the deposited volume mainly depends on the capillary-substrate distance and the anchor surface wettability. A critical equilibrium contact angle has been identified below which reproducible depositions are facilitated.

Place, publisher, year, edition, pages
2007. Vol. 23, no 3, 1171-1177 p.
Keyword [en]
Contact angle; Deposition; Finite element method; Gravitational effects; Mathematical models; Navier Stokes equations; Surface tension; Cahn Hilliard equations; Liquid mediums; Microdroplet deposition; Pressure pulses; Fluid dynamics; article; mathematical computing; particle size; reproducibility; solution and solubility; surface tension; technique; wettability; Methods; Numerical Analysis, Computer-Assisted; Particle Size; Reproducibility of Results; Solutions; Surface Tension; Wettability
National Category
Other Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-7213DOI: 10.1021/la0626712ISI: 000243684100035PubMedID: 17241029Scopus ID: 2-s2.0-33847175859OAI: oai:DiVA.org:kth-7213DiVA: diva2:12154
Note
QC 20100823Available from: 2007-05-29 Created: 2007-05-29 Last updated: 2017-12-14Bibliographically approved
In thesis
1. Diffuse-Interface Simulations of Capillary Phenomena
Open this publication in new window or tab >>Diffuse-Interface Simulations of Capillary Phenomena
2007 (English)Doctoral thesis, comprehensive summary (Other scientific)
Abstract [en]

Fluid flows mainly driven by capillary forces are presented in this thesis. By means of modeling and simulations, interesting dynamics in capillary-driven flows are revealed such as coalescences, breakups, precursor films, flow instabilities, rapid spreading, rigid body motions, and reactive wetting.

Diffuse-interface methods model a fluid interface as having a finite thickness endowed with physical properties such as surface tension. Two diffuse-interface models that are based on the free energy of the system are presented. The binary model, more specifically the coupled Navier-Stokes/Cahn-Hilliard equations, was used to study different two-phase flows including problems related to microfluidics. Numerical issues using this model have been addressed such as the need for mesh adaptivity and time-step restrictions. Moreover, the flexibility of this model to simulate 2D, axisymmetric, and 3D flows has been demonstrated.

The factors affecting reproducibility of microdroplet depositions performed under a liquid medium are investigated. In the deposition procedure, sample solution is dispensed from the end of a capillary by the aid of a pressure pulse onto a substrate with pillar-shaped sample anchors. In both the experimental and numerical study it was shown that the deposited volume mainly depends on the capillary-substrate distance and anchor surface wettability. Furthermore, a critical equilibrium contact angle has been identified below which reproducible depositions are facilitated.

The ternary model is developed for more complicated flows such as liquid phase sintering. With the introduction of a Gibbs energy functional, the governing equations are derived, consisting of convective concentration and phase-field equations which are coupled to the Navier-Stokes equations with surface tension forces. Arbitrary phase diagrams, surface energies, and typical dimensionless numbers are some input parameters into the model. Detailed analysis of the important capillary phenomena in liquid phase sintering such as reactive and nonreactive wetting and motion of two particles connected by a liquid bridge are presented. The dynamics of the wetting is found to match with a known hydrodynamic theory for spreading liquids. Factors affecting the equilibrium configuration of the particles such as equilibrium contact angles and volume ratios are also investigated.

Place, publisher, year, edition, pages
Stockholm: KTH, 2007. ix, 34 p.
Series
Trita-MEK, ISSN 0348-467X ; 2007:05
Keyword
capillary-driven flows, wetting, Cahn-Hilliard/Navier-Stokes system, multicomponent and multiphase flows, parallel adaptive computing
National Category
Other Materials Engineering
Identifiers
urn:nbn:se:kth:diva-4402 (URN)978-91-7178-718-7 (ISBN)
Public defence
2007-06-08, Sal F2, KTH, Lindstedtsvägen 26, Stockholm, 10:00 (English)
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Note
QC 20100823Available from: 2007-05-29 Created: 2007-05-29 Last updated: 2010-08-23Bibliographically approved

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