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Metal-Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent
Dalian Univ Technol, Inst Artificial Photosynthesis, State Key Lab Fine Chem, Dalian 116024, Peoples R China..
Dalian Univ Technol, Inst Artificial Photosynthesis, State Key Lab Fine Chem, Dalian 116024, Peoples R China..ORCID iD: 0000-0002-6306-1359
Dalian Univ Technol, Inst Artificial Photosynthesis, State Key Lab Fine Chem, Dalian 116024, Peoples R China..
KTH, School of Chemical Science and Engineering (CHE), Centres, Centre of Molecular Devices, CMD. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry. Dalian Univ Technol, Inst Artificial Photosynthesis, State Key Lab Fine Chem, Dalian 116024, Peoples R China.;KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Chem, S-10044 Stockholm, Sweden..ORCID iD: 0000-0002-4521-2870
2018 (English)In: Materials, ISSN 1996-1944, E-ISSN 1996-1944, Vol. 11, no 10, article id 1868Article in journal (Refereed) Published
Abstract [en]

Metal-organic framework thin film-based dye sensitized solar cell is fabricated with highly oriented, crystalline, and porous Zn-perylene metal-organic framework (MOF) thin film (SURMOF) which is integrated with Bodipy embedded in poly(methyl methacrylate). It has been demonstrated that the photocurrent can be enhanced by a factor of 5 relative to Zn-perylene MOF thin film due to triplet-triplet annihilation up-conversion between the Bodipy/PMMA sensitizer and the Zn-perylene MOF thin film acceptor using Co(bpy)(3)(2+/3+) as redox mediator.

Place, publisher, year, edition, pages
MDPI, 2018. Vol. 11, no 10, article id 1868
Keywords [en]
surface supported metal organic framework, triplet-triplet annihilation upconversion, triplet-triplet energy transfer, dye sensitized solar cell
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-239104DOI: 10.3390/ma11101868ISI: 000448658400082PubMedID: 30275372Scopus ID: 2-s2.0-85054254559OAI: oai:DiVA.org:kth-239104DiVA, id: diva2:1264732
Note

QC 20181121

Available from: 2018-11-21 Created: 2018-11-21 Last updated: 2019-03-18Bibliographically approved

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Sun, Licheng

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