A thermodynamic analysis of the Mo-V and Mo-V-C systems
2002 (English)In: Calphad, ISSN 0364-5916, E-ISSN 1873-2984, Vol. 26, no 3, 459-503 p.Article in journal (Refereed) Published
A new thermodynamic evaluation of the binary Mo-V system and the ternary Mo-V-C system using thermodynamic models for the Gibbs energy of individual phases is presented. The CALPHAD method has been used, with predictions of unknown thermodynamic quantities, to optimize a set of thermodynamic parameters taking related experimental information into consideration. The predictions are based on regularities in bonding properties and vibrational entropy of 3d-transition metal carbides. The results are summarized in tables of thermodynamic parameters, calculated binary phase diagrams and isothermal sections of the ternary phase diagram compared with experimental information. Finally the influence of ternary interaction parameters, especially in the fcc phase, on calculations of equilibria in multicomponent systems is discussed.
Place, publisher, year, edition, pages
2002. Vol. 26, no 3, 459-503 p.
Binary alloys, Carbides, Entropy, Gibbs free energy, Isotherms, Molybdenum, Optimization, Phase diagrams, Binary systems
IdentifiersURN: urn:nbn:se:kth:diva-7606DOI: 10.1016/S0364-5916(02)00057-3ISI: 000179541200011OAI: oai:DiVA.org:kth-7606DiVA: diva2:12688
QC 201009292005-10-182005-10-182010-09-29Bibliographically approved