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The one pot synthesis of heterobimetallic complexes from a homoditopic pyrimidine–hydrazone ligand
Department of Chemistry, University of Otago.ORCID iD: 0000-0003-0028-1204
Department of Chemistry, University of Otago.ORCID iD: 0000-0003-4004-9565
Department of Chemistry, University of Otago.
2014 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, no 28, p. 14550-14556Article in journal (Refereed) Published
Abstract [en]

The symmetrical, homoditopic, pyrimidine-hydrazone (pym-hyz) ligand L1 was used to synthesise three new heterobimetallic complexes, CuPbL1(ClO4)4, CuAgL1(SO3CF3)3, and CuZnL1(SO3CF3)4. Each of the complexes was produced in a one-pot reaction in CH3CN, and was isolated in high yield and purity simply by precipitation through the addition of diethyl ether. Analysis was carried out by IR, UV-Vis and ESMS spectroscopy, as well as microanalysis. Crystals were also grown for the purposes of X-ray diffraction studies, which yielded the structures [CuPbL1(ClO4)(CH3CN)2(H2O)](ClO4)3(1),[CuAgL1(SO3CF3)(CH3CN)2](SO3CF3)2$CH3CN (2), and CuZnL1(SO3CF3)2(CH3CN)(H2O)](SO3CF3)2$CH3CN (3), all of which were linear complexes containing a Cu(II) ion in one of the pym-hyz-py coordination sites, and either a Pb(II), Ag(I), or Zn(II) ion in the other.

Place, publisher, year, edition, pages
2014. Vol. 4, no 28, p. 14550-14556
National Category
Inorganic Chemistry
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URN: urn:nbn:se:kth:diva-240977Scopus ID: 2-s2.0-84897087930OAI: oai:DiVA.org:kth-240977DiVA, id: diva2:1275559
Note

QC 20190108

Available from: 2019-01-07 Created: 2019-01-07 Last updated: 2019-01-08Bibliographically approved

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