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2-Methyl-4,6-bis-(1-methyl-hydrazino)pyrimidine
Department of Chemistry, University of Otago.ORCID iD: 0000-0003-0028-1204
Department of Chemistry, University of Otago.ORCID iD: 0000-0003-4004-9565
Department of Chemistry, University of Otago.
2009 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 65, no Pt 7, p. o1546-Article in journal (Refereed) Published
Abstract [en]

In the title compound, C(7)H(14)N(6), the amine groups of the two methyl-hydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The mol-ecule is almost planar with only the two amine N atoms lying substanti-ally out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) A]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the mol-ecule. Each mol-ecule is linked to two others through N-Hcdots, three dots, centeredN hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face pi-pi stacking inter-actions between the pyrimidine rings organize these chains into a two-dimensional array [centroid-centroid distance = 3.789 (2) A].

Place, publisher, year, edition, pages
2009. Vol. 65, no Pt 7, p. o1546-
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-240972DOI: 10.1107/S1600536809021643ISBN: 1600-5368 (Print) 1600-5368 (Linking) OAI: oai:DiVA.org:kth-240972DiVA, id: diva2:1275582
Note

QC 20190108

Available from: 2019-01-07 Created: 2019-01-07 Last updated: 2019-01-08Bibliographically approved

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Publisher's full texthttps://www.ncbi.nlm.nih.gov/pubmed/21582832

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