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Raman high-pressure study of butane isomers up to 40 GPa
KTH, School of Industrial Engineering and Management (ITM), Energy Technology.
KTH, School of Industrial Engineering and Management (ITM), Energy Technology.ORCID iD: 0000-0001-8199-5625
2018 (English)In: AIP Advances, ISSN 2158-3226, E-ISSN 2158-3226, Vol. 8, no 11, article id 115104Article in journal (Refereed) Published
Abstract [en]

Raman spectroscopy studies on n and i-butane were performed at pressures of up to 40 GPa at ambient temperatures using the DAC technique. Normal butane undergoes two phase transitions at 1.9(5) GPa and 2.9(5) GPa and isobutane at 2.7(5) GPa and 3.5(5) GPa. These phase transitions were identified based on observations of the splitting Raman modes and the appearance or disappearance of particular Raman peaks. Our results demonstrate the complex, high-pressure behavior of butane isomers.

Place, publisher, year, edition, pages
American Institute of Physics Inc. , 2018. Vol. 8, no 11, article id 115104
Keywords [en]
Butane, Butane isomers, High pressure study, High-pressure behavior, I-butane, Isobutanes, Raman modes, Raman peak, Isomers
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-247098DOI: 10.1063/1.5049481ISI: 000451737400039Scopus ID: 2-s2.0-85056078826OAI: oai:DiVA.org:kth-247098DiVA, id: diva2:1302255
Note

QC 20190404

Available from: 2019-04-04 Created: 2019-04-04 Last updated: 2019-04-04Bibliographically approved

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Kudriavtcev, DanilKutcherov, Vladimir G.

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