Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Accumulation of heavy metals in the Oostriku peat bog, Estonia: Determination of binding processes by means of sequential leaching.
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology.
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology.ORCID iD: 0000-0002-4530-3414
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology.
2007 (English)In: Environmental Pollution, ISSN 0269-7491, E-ISSN 1873-6424, Vol. 147, no 1, 291-300 p.Article in journal (Refereed) Published
Abstract [en]

The Oostriku peat bog (central Estonia) has been exposed to metal-rich groundwater discharge over a long period of time and has accumulated high concentrations of Fe (up to 40 wt-%), heavy metals (e.g. Ph, Zn, Mn, Cu), and As. In this study, the peat was characterised with respect to composition and metal content with depth. The peat pore water was analysed and compared to a spring water emerging at the site. Sequential extraction, using a Tessier scheme optimised for iron-rich sediments, was used to understand the relative roles of binding mechanisms involved in the retention of different metals in the peat. Significant difference in depth distribution was found between different metals bound in the peat, which was partly attributed to varying compositions of the peat with depth and different dominant binding mechanisms for different metals.

Place, publisher, year, edition, pages
2007. Vol. 147, no 1, 291-300 p.
Keyword [en]
peat bog, aqueous composition, heavy metal distribution, sequential extraction, binding mechanisms
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-7879DOI: 10.1016/j.envpol.2005.10.048ISI: 000245475400035Scopus ID: 2-s2.0-33847379862OAI: oai:DiVA.org:kth-7879DiVA: diva2:13037
Note
Tidigare titel: Accumulation of heavy metals in the Oostriku peat bog: determination of binding processes by means of sequential extraction. QC 20101001Available from: 2005-10-21 Created: 2005-10-21 Last updated: 2017-12-14Bibliographically approved
In thesis
1. Long-term metal retention processes in a peat bog: Field studies, data and modelling
Open this publication in new window or tab >>Long-term metal retention processes in a peat bog: Field studies, data and modelling
2005 (English)Doctoral thesis, comprehensive summary (Other scientific)
Abstract [en]

The study was inspired by the need to assess long-term metal retention in municipal solid waste (MSW) landfills. The long-term processes in landfills are poorly known due to the relatively short time that such landfills have been in existence. Natural analogues where similar metal binding processes could be expected were therefore sought for.

The work described in this thesis aims to elucidate the long-term transport and attenuation processes involved in the retention of heavy metals in a peat bog, through field studies and modelling. The Oostriku peat bog (central Estonia) has been exposed to metal-rich groundwater discharge over a long period of time and was found to have accumulated high concentrations of Fe, other heavy metals (e.g. Pb, Cu, Zn, Mn), and As. It was characterised in detail with respect to metal depth distribution and main metal binding mechanisms (using an optimised Tessier extraction scheme).

The oxidation of metal sulphides in the surrounding carbonate bedrock was proposed to be a possible long-term source of heavy metals in the water emerging in a spring at the peat site. The water in the spring and peat pore-water was sampled and analysed. The dissolution sequence of the sulphide minerals and evolution of the water composition along a flowpath in the carbonate rock were modelled. Resulting aqueous phase concentration of major and minor elements are discussed in relation to governing geochemical processes. The simulated water composition was compared with that observed.

Retention of metals transported with water through the peat was assessed through modelling equilibrium sorption on solid organic matter and amorphous ferric oxyhydroxide by using a simplified quantitative modelling approach and independently obtained data. Dynamic evolution of metal sorption fronts along a peat profile over time was modelled to test metal-metal competition effects. A possible formation of ferric oxyhydroxide in the peat bog was also assessed with the model.

Place, publisher, year, edition, pages
Stockholm,: KTH, 2005. vi, 80 p.
Series
Trita-KET, ISSN 1104-3466 ; 219
Keyword
Peat, heavy metals distribution, sequential extraction, binding mechanisms, modelling, metal sulphide oxidation, aqueous composition, sorption, humic substances, ferric oxyhydroxide
National Category
Chemical Engineering
Identifiers
urn:nbn:se:kth:diva-460 (URN)91-7178-164-1 (ISBN)
Public defence
2005-11-03, D3, Lindstedtsväg 5, EntrePlan, Stockholm, 10:00
Opponent
Supervisors
Note
QC 20101001Available from: 2005-10-21 Created: 2005-10-21 Last updated: 2010-10-01Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Malmström, Maria E.

Search in DiVA

By author/editor
Syrovetnik, KristinaMalmström, Maria E.Neretnieks, Ivars
By organisation
Chemical Engineering and Technology
In the same journal
Environmental Pollution
Chemical Engineering

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 124 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf