Stereoselective Synthesis of Polyhydroxyl Surfactants. Stereochemical Influence on Langmuir Monolayers
2004 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 69, no 11, 3746-3752 p.Article in journal (Refereed) Published
Herein is described the synthesis of surfactants featuring polyhydroxylated head groups. Three head groups were prepared via consecutive stereoselective dihydroxylations of a diene. By coupling of these with lipophilic tail groups six novel surfactants have been prepared. The monolayers prepared from four of these have been investigated at the air-water interface. Significant differences were observed between monolayers consisting of enantiomerically pure surfactants contra racemates as well as between diastereomers.
Place, publisher, year, edition, pages
2004. Vol. 69, no 11, 3746-3752 p.
Interfaces (materials), Isomers, Monolayers, Stereochemistry, Synthesis (chemical), article, diastereoisomer, enantiomer, hydroxylation, lipophilicity, racemic mixture, stereochemistry, synthesis
Organic Chemistry Physical Chemistry
IdentifiersURN: urn:nbn:se:kth:diva-7903DOI: 10.1021/jo0357566ISI: 000221624900018ScopusID: 2-s2.0-2442704158OAI: oai:DiVA.org:kth-7903DiVA: diva2:13072
QC 201009302005-10-212005-10-212016-05-18Bibliographically approved