One-Pot Difunctionalization of Poly-(ω-pentadecalactone) with Thiol-Thiol or Thiol-Acrylate Groups, Catalyzed by Candida antarctica Lipase B
2006 (English)In: Macromolecular rapid communications, ISSN 1022-1336, E-ISSN 1521-3927, Vol. 27, no 22, 1932-1936 p.Article in journal (Refereed) Published
An enzymatic one-pot procedure has been developed for the synthesis of difunetional polyesters containing terminal thiols and acrylates. Candida antarctica lipase B was used as a catalyst for the ring-opening polymerization of ω-pentadecalactone. The polymerization was initiated with 6-mercaptohexanol, then terminated with γ-thiobutyrolactone or vinyl acrylate to create two types of difunetional polyesters with a very high content of thiol-thiol or thiolacrylate end-groups.
Place, publisher, year, edition, pages
2006. Vol. 27, no 22, 1932-1936 p.
Biocatalysis, Enzymes, Polyesters, Ring-opening polymerization
Biochemistry and Molecular Biology
IdentifiersURN: urn:nbn:se:kth:diva-8003DOI: 10.1002/marc.200600527ISI: 000242616900008ScopusID: 2-s2.0-33845199474OAI: oai:DiVA.org:kth-8003DiVA: diva2:13206
QC 201009242008-02-202008-02-202010-10-06Bibliographically approved