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Copper-Plated Paper for High-Performance Lithium-Ion Batteries
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology.
KTH.
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Fibre Technology.
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2018 (English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, Vol. 14, no 48, article id 1803313Article in journal (Refereed) Published
Abstract [en]

Paper is emerging as a promising flexible, high surface-area substrate for various new applications such as printed electronics, energy storage, and paper-based diagnostics. Many applications, however, require paper that reaches metallic conductivity levels, ideally at low cost. Here, an aqueous electroless copper-plating method is presented, which forms a conducting thin film of fused copper nanoparticles on the surface of the cellulose fibers. This paper can be used as a current collector for anodes of lithium-ion batteries. Owing to the porous structure and the large surface area of cellulose fibers, the copper-plated paper-based half-cell of the lithium-ion battery exhibits excellent rate performance and cycling stability, and even outperforms commercially available planar copper foil-based anode at ultra-high charge/discharge rates of 100 C and 200 C. This mechanically robust metallic-paper composite has promising applications as the current collector for light-weight, flexible, and foldable paper-based 3D Li-ion battery anodes.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2018. Vol. 14, no 48, article id 1803313
Keywords [en]
copper-plating, lithium-ion batteries, paper, Anodes, Cellulose, Copper plating, Electric current collectors, Flexible electronics, Ions, Natural fibers, Substrates, Textile fibers, Copper nanoparticles, Cycling stability, Electroless copper plating, High-performance lithium-ion batteries, Large surface area, Mechanically robust, Metallic conductivity, Printed electronics
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-247036DOI: 10.1002/smll.201803313ISI: 000451566800015PubMedID: 30328292Scopus ID: 2-s2.0-85055060094OAI: oai:DiVA.org:kth-247036DiVA, id: diva2:1330277
Note

QC 20190625

Available from: 2019-06-25 Created: 2019-06-25 Last updated: 2019-09-18Bibliographically approved

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Wang, ZhenOuyang, LiangqiTian, WeiqianWågberg, LarsHamedi, Mahiar

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Wang, ZhenMalti, AbdellahOuyang, LiangqiTian, WeiqianWågberg, LarsHamedi, Mahiar
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