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Silver-Induced [3+2] Cycloaddition of Isocyanides with Acyl Chlorides: Regioselective Synthesis of 2,5-Disubstituted Oxazoles
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Organic chemistry. Jiangsu Normal Univ, Jiangsu Key Lab Green Synth Funct Mat, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China.
Jiangsu Normal Univ, Jiangsu Key Lab Green Synth Funct Mat, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Organic chemistry.
Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271000, Shandong, Peoples R China..
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2019 (English)In: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899Article in journal (Refereed) Epub ahead of print
Abstract [en]

A silver-induced cycloaddition of isocyanides with acyl chlorides has been developed. This transition metal-catalyzed strategy provides an effective and scalable approach for the formation of 2,5-disubstituted oxazoles in good to high yields. The employed silver-based MOF catalyst can be efficiently recycled without compromising the yield.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2019.
Keywords [en]
acyl chlorides, cycloaddition, isocyanides, oxazoles, silver
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-255373DOI: 10.1002/cctc.201900965ISI: 000475111400001OAI: oai:DiVA.org:kth-255373DiVA, id: diva2:1341231
Note

QC 20190808

Available from: 2019-08-08 Created: 2019-08-08 Last updated: 2019-08-08Bibliographically approved

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Shatskiy, AndreyKärkäs, Markus D.

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