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A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction
KTH, School of Engineering Sciences (SCI), Applied Physics. Uppsala Univ, Dept Chem, Angstrom Lab, Box 523, SE-75120 Uppsala, Sweden.
Uppsala Univ, Dept Chem, Angstrom Lab, Box 523, SE-75120 Uppsala, Sweden..
Uppsala Univ, Dept Chem, Angstrom Lab, Box 523, SE-75120 Uppsala, Sweden..
Uppsala Univ, Dept Chem, Angstrom Lab, Box 523, SE-75120 Uppsala, Sweden..
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 55, p. 7918-7921Article in journal (Refereed) Published
Abstract [en]

Heavy metal-free CuInS2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO2 reduction for the first time. A photocurrent of 25 mu A cm(-2) at -0.87 V vs. NHE was obtained, providing a faradaic efficiency of 32% for CO production.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2019. Vol. 55, no 55, p. 7918-7921
National Category
Chemical Sciences
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URN: urn:nbn:se:kth:diva-255371DOI: 10.1039/c9cc04222aISI: 000474306200003PubMedID: 31215919Scopus ID: 2-s2.0-85068517908OAI: oai:DiVA.org:kth-255371DiVA, id: diva2:1341253
Note

QC 20190808

Available from: 2019-08-08 Created: 2019-08-08 Last updated: 2019-08-08Bibliographically approved

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