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Solution mediated phase transformations between co-crystals
2013 (English)In: CrystEngComm, Vol. 15, no 11, p. 2044-2047Article in journal (Refereed) Published
Abstract [en]

A solution mediated transformation between two co-crystal phases has been observed for the p-toluensulfonamide-triphenylphosphine oxide co-crystal system. This system has two known co-crystals with 1 : 1 and 3 : 2 stoichiometry respectively, and the ternary phase diagram (TPD) for the system has been determined in acetonitrile previously. By manipulating the solution composition in this solvent to a region of the TPD where the 1 : 1 co-crystal is stable, the 3 : 2 co-crystal could be observed to convert to the 1 : 1 co-crystal. The corresponding transformation was true for the 1 : 1 co-crystal in a region of the TPD where the 3 : 2 co-crystal is stable; the 1 : 1 co-crystal converted to the 3 : 2 co-crystal.

Place, publisher, year, edition, pages
2013. Vol. 15, no 11, p. 2044-2047
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-260457DOI: 10.1039/c2ce26801aISI: 000315163800003Scopus ID: 2-s2.0-84874160460OAI: oai:DiVA.org:kth-260457DiVA, id: diva2:1355632
Note

QC 20190930

Available from: 2019-09-30 Created: 2019-09-30 Last updated: 2019-09-30Bibliographically approved

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