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Transition metal-catalyzed cross-coupling methodologies for the engineering of small molecules with applications in organic electronics and photovoltaics
CNR, Ist Chim Composti Organometallici, ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy..ORCID iD: 0000-0003-0621-2648
CNR, Ist Chim Composti Organometallici, ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy..ORCID iD: 0000-0003-2358-227X
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Organic chemistry. CNR, Ist Chim Composti Organometallici, ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy.;Univ Firenze, Dipartimento Chim Ugo Schiff, Via Lastruccia 13, I-50019 Sesto Fiorentino, Italy.ORCID iD: 0000-0003-2811-247x
CNR, Ist Chim Composti Organometallici, ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy.;Univ Firenze, Dipartimento Chim Ugo Schiff, Via Lastruccia 13, I-50019 Sesto Fiorentino, Italy..
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2019 (English)In: Coordination chemistry reviews, ISSN 0010-8545, E-ISSN 1873-3840, Vol. 392, p. 177-236Article, review/survey (Refereed) Published
Abstract [en]

Cross-coupling reactions have played a key role in producing numerous types of it-conjugated small molecules having appealing properties for practical applications in organic electronics, especially in the field of photovoltaics. The main advantages of such synthetic methodology are the compatibility with many types of functional groups and the flexibility which allows an easy way to introduce diversity and tune the electronic and photophysical properties of the target molecules. As a result, many semiconducting and photoactive organic compounds have been synthesized using this powerful tool. In this paper we will highlight a number of selected syntheses and optimized C-C bond formation processes described in the years 2000-2018 and related to this specific field, choosing those examples which can demonstrate the enormous power of the cross-coupling processes, but also the room for improvements of these methodologies.

Place, publisher, year, edition, pages
Elsevier, 2019. Vol. 392, p. 177-236
Keywords [en]
Cross-coupling reactions, Organic electronics, Photovoltaics, Suzuki-Miyaura reaction, Stille-Migita reaction, C-H activation
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-270819DOI: 10.1016/j.ccr.2019.04.007ISI: 000470945400006Scopus ID: 2-s2.0-85065528818OAI: oai:DiVA.org:kth-270819DiVA, id: diva2:1414564
Note

QC 20200313

Available from: 2020-03-13 Created: 2020-03-13 Last updated: 2020-03-13Bibliographically approved

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Franchi, Daniele

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