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Flammability and mechanical properties of biochars made in different pyrolysis reactors
Luleå Univ Technol, Dept Civil Environm & Nat Resources Engn, Struct & Fire Engn Div, S-97187 Luleå, Sweden..
Nanjing Univ Sci & Technol, Sch Mech Engn, Nanjing 210094, Peoples R China..
St Berchmans Coll, Res & Post Grad Dept Chem, Changanacheri, Kerala, India..
Nanjing Univ Sci & Technol, Sch Mech Engn, Nanjing 210094, Peoples R China..
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2021 (English)In: Biomass and Bioenergy, ISSN 0961-9534, E-ISSN 1873-2909, Vol. 152, article id 106197Article in journal (Refereed) Published
Abstract [en]

The effect of pyrolysis reactors on the properties of biochars (with a focus on flammability and mechanical characteristics) were investigated by keeping factors such as feedstock, carbonisation temperature, heating rate and residence time constant. The reactors employed were hydrothermal, fixed-bed batch vertical and fixed-bed batch horizontal-tube reactors. The vertical and tube reactors, at the same temperature, produced biochars having comparable elemental carbon content, surface functionalities, thermal degradation pattern and peak heat release rates. The hydrothermal reactor, although, a low-temperature process, produced biochar with high fire resistance because the formed tarry volatiles sealed water inside the pores, which hindered combustion. However, the biochar from hydrothermal reactor had the lowest nanoindentation properties whereas the tube reactor-produced biochar at 300 degrees C had the highest nanoindentation-hardness (290 Megapascal) and modulus (ca. 4 Gigapascal) amongst the other tested samples. Based on the inherent flammability and mechanical properties of biochars, polymeric composites' properties can be predicted that can include them as constituents.

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2021. Vol. 152, article id 106197
Keywords [en]
Biochar, Carbonisation, Flammability, Nanoindentation, Composites
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-300819DOI: 10.1016/j.biombioe.2021.106197ISI: 000686120900003Scopus ID: 2-s2.0-85111300252OAI: oai:DiVA.org:kth-300819DiVA, id: diva2:1598712
Note

QC 20210929

Available from: 2021-09-29 Created: 2021-09-29 Last updated: 2022-06-25Bibliographically approved

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Hedenqvist, Mikael S.

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