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Sandwich-Type Zeolite Intergrowths with MFI and the Novel Extra-Large Pore IDM-1 as Ordered End-Members
Univ Valencia, Univ Politecn Valencia, Inst Interuniv Invest Reconocimiento Mol & Desarr, Valencia 46022, Spain.;CIBER Bioingn Biomat & Nanomed CIBER BBN, Valencia 46022, Spain.;Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology. Stockholm Univ, Berzelii Ctr EXSELENT Porous Mat, Dept Mat & Environm Chem, S-10691 Stockholm, Sweden..ORCID iD: 0000-0003-2221-2285
Univ Zaragoza, Inst Nanociencia & Mat Aragon INMA CSIC, Zaragoza 50009, Spain.;ShanghaiTech Univ, Sch Phys Sci & Technol, Ctr High Resolut Electron Microscopy ChEM, Lab Microscopias Avanzadas LMA Univ Zaragoza, Shanghai 201210, Peoples R China..ORCID iD: 0000-0002-5229-2717
Consejo Super Invest Cient ICMM CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain..
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2021 (English)In: Chemistry of Materials, ISSN 0897-4756, E-ISSN 1520-5002, Vol. 33, no 19, p. 7869-7877Article in journal (Refereed) Published
Abstract [en]

Stacking faults are two-dimensional planar defects frequently arising in zeolites, modifying their properties and potentially affecting their performance in catalysis and separation applications. In classical zeolite intergrowths, a topologically unique zeolite layer may often pile up after some spatial transformation (lateral translation, rotation, and/or reflection) that may occur in different amounts or directions with about similar probabilities, leading to a difficult to control disorder. Here, we present a new kind of zeolite intergrowth that requires an additional topologically distinct layer rather than a spatial transformation of a unique one. Stacking of the so-called pentasil layers produces the well-known medium pore zeolite MFI. Intercalation in strict alternation of a topologically distinct second layer sandwiched between pentasil layers expands the structure to produce the new extra-large pore IDM-1. Stacking disorder modulates the structural expansion along the stacking direction. The disordered materials have been studied by simulation of the X-ray diffraction patterns using the program DIFFaX and by Cs-corrected high-resolution electron microscopy. We show that disorder does not occur at random but in extended domains and can be controlled all the way from MFI to IDM-1 by just varying the concentration of the synthesis mixture.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2021. Vol. 33, no 19, p. 7869-7877
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:kth:diva-304717DOI: 10.1021/acs.chemmater.1c02631ISI: 000708647800028Scopus ID: 2-s2.0-85117094262OAI: oai:DiVA.org:kth-304717DiVA, id: diva2:1610224
Note

QC 20211110

Available from: 2021-11-10 Created: 2021-11-10 Last updated: 2025-02-18Bibliographically approved

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Li, Jian

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