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Anion Specific Effects at Negatively Charged Interfaces: Influence of Cl-, Br-, I-, and SCN- on the Interactions of Na+ with the Carboxylic Acid Moiety
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0001-8624-3377
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0003-1221-0227
2021 (English)In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 125, no 44, p. 12384-12391Article in journal (Refereed) Published
Abstract [en]

Unlike counterion interactions with charged interfaces, the influence of co-ions is only scarcely reported in the literature. In this work, the effect of SCN- and the halide co-ions in the interactions of Na+ with carboxylic acid Langmuir monolayers is investigated by using vibrational sum frequency spectroscopy. At 1 M concentrations in the subphase, the identity of the anion is shown to have a remarkable influence on the charging behavior and degree of deprotonation of the monolayer, with ions ordering in the sequence I- > SCN- > Cl- approximate to Br-. The same trend is observed at both pH 6 and pH 9 when the monolayer is intrinsically more charged. Spectroscopic evidence is found for both the presence of I- and SCN- in the interfacial region at levels close to their detection limits. The results contradict electrostatic theories on charged interfaces where co-ions are not expected to play any significant role. The higher propensity for the large polarizable anions to deprotonate the monolayer is explained in terms of their ability to modify the cations affinity toward the carboxylic acid groups present at the surface.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2021. Vol. 125, no 44, p. 12384-12391
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-305336DOI: 10.1021/acs.jpcb.1c07758ISI: 000718392400026PubMedID: 34705447Scopus ID: 2-s2.0-85118945182OAI: oai:DiVA.org:kth-305336DiVA, id: diva2:1615759
Note

QC 20211201

Available from: 2021-12-01 Created: 2021-12-01 Last updated: 2022-06-25Bibliographically approved

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Sthoer, AdrienTyrode, Eric

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