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Assessment of Q(OP)D(PO) bleachability of softwood kraft pulp
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology. Svenska Cellulosa Aktiebolaget SCA, Sundsvall, Sweden.;Mid Sweden Univ, Sundsvall, Sweden..
Svenska Cellulosa Aktiebolaget SCA, Sundsvall, Sweden..
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.ORCID iD: 0000-0001-7433-0350
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.ORCID iD: 0000-0002-2900-4713
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2021 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 36, no 4, p. 582-593Article in journal (Refereed) Published
Abstract [en]

Bleachability is evaluated as how easily a pulp sample is bleached and it depends on the structure of residual lignin and carbohydrates. Also, the bleachability varies depending on the bleaching sequence. ECF light sequences have been improved significantly in the recent years. However, we still don't fully understand how ECF light bleach plants are optimally run. This work studies the bleachability of softwood kraft pulp in an ECF light bleaching sequence, (OO)Q(OP)D(PO). Three pulp samples with brown stock kappa number 27, 32 and 35 were bleached and studied for residual lignin, hexenuronic acid and carbohydrate content. It was found that in the bleaching stages that are highly delignifying, it is beneficial with a higher kappa number for the delignifying bleachability. However, in the bleaching stages where the objective is brightness increase, the brightness gain bleachability is improved by a lower kappa number. We also intended to determine which of the three samples had the best suited kappa number for this particular bleaching sequence. According to our results, the bleaching was most effective with kappa number around 32. Although an even higher kappa number resulted in higher yield after cooking, it seemed that this bleaching sequence cannot preserve the yield gain.

Place, publisher, year, edition, pages
Walter de Gruyter GmbH , 2021. Vol. 36, no 4, p. 582-593
Keywords [en]
brightness gain, chlorine dioxide, delignification, ECF light bleaching, kappa number
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:kth:diva-309304DOI: 10.1515/npprj-2021-0022ISI: 000753926000004Scopus ID: 2-s2.0-85116586695OAI: oai:DiVA.org:kth-309304DiVA, id: diva2:1641288
Note

QC 20220301

Available from: 2022-03-01 Created: 2022-03-01 Last updated: 2022-06-25Bibliographically approved

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Starrsjö, SaraSevastyanova, OlenaLindström, Mikael

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