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Materials for high temperature liquid lead storage for concentrated solar power (Csp) air tower systems
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0001-6047-9496
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2021 (English)In: Materials, E-ISSN 1996-1944, Vol. 14, no 12, article id 3261Article in journal (Refereed) Published
Abstract [en]

Today the technical limit for solar towers is represented by the temperature that can be reached with current accumulation and exchange fluids (molten salts are generally adopted and the max temperatures are generally below 600◦ C), even if other solutions have been suggested that reach 800◦ C. An innovative solution based on liquid lead has been proposed in an ongoing experimental project named Nextower. The Nextower project aims to improve current technologies of the solar sector by transferring experience, originally consolidated in the field of nuclear plants, to accumulate heat at higher temperatures (T = 850–900◦ C) through the use of liquid lead heat exchangers. The adoption of molten lead as a heat exchange fluid poses important criticalities of both corrosion and creep resistance, due to the temperatures and structural stresses reached during service. Liquid lead corrosion issues and solutions in addition to creep-resistant material selection are discussed. The experimental activities focused on technical solutions adopted to overcome these problems in terms of the selected materials and technologies. Corrosion laboratory tests have been designed in order to verify if structural 800H steel coated with 6 mm of FeCrAl alloy layers are able to resist the liquid lead attack up to 900◦ C and for 1000 h or more. The metallographic results were obtained by mean of scanning electron microscopy with an energy dispersive microprobe confirm that the 800H steel shows no sign of corrosion after the completion of the tests. 

Place, publisher, year, edition, pages
MDPI AG , 2021. Vol. 14, no 12, article id 3261
Keywords [en]
Alloy 800H, FeCrAl alloys, Lead corrosion, Solar concentrated towers, Solar system, Aluminum alloys, Aluminum metallography, Chromium alloys, Chromium metallography, Creep, Creep resistance, Heat exchangers, Heat resistance, Iron alloys, Iron metallography, Liquids, Scanning electron microscopy, Solar power plants, Steel corrosion, Steel testing, Ternary alloys, Concentrated solar power, Experimental activities, Experimental projects, Heat exchange fluids, High-temperature liquids, Innovative solutions, Materials and technologies, Technical solutions, Corrosion resistant coatings
National Category
Metallurgy and Metallic Materials Surface- and Corrosion Engineering
Identifiers
URN: urn:nbn:se:kth:diva-310151DOI: 10.3390/ma14123261ISI: 000666473500001PubMedID: 34204775Scopus ID: 2-s2.0-85108591750OAI: oai:DiVA.org:kth-310151DiVA, id: diva2:1648293
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QC 20220330

Available from: 2022-03-30 Created: 2022-03-30 Last updated: 2025-02-09Bibliographically approved

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Szakalos, Peter

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