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Revisiting the Theory of Coagulation of Colloidal Dispersions: An Improved Expression for the Stability Ratio
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemical Engineering. China Inst Atom Energy, Dept Radiochem, Beijing 102413, Peoples R China.;KTH Royal Inst Technol, Dept Chem Engn, S-10044 Stockholm, Sweden..ORCID iD: 0000-0001-6801-9208
Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Peoples R China.;Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China..ORCID iD: 0000-0002-2128-2057
Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.;Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China..
Univ South China, R&D & Modelling Ctr Treatment & Disposal Radioact, Hengyang 421001, Peoples R China.;Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Peoples R China..
2022 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 38, no 3, p. 1131-1140Article in journal (Refereed) Published
Abstract [en]

The stability of a colloidal dispersion has long been expressed in terms of the stability ratio. Based on the available theories of coagulation of colloidal dispersions, a novel expression, complying with the classical definition, is developed for the stability ratio. It accounts for the contributions of both primary and secondary minimum coagulations to the overall rate of coagulations. In addition, it can also be regarded as the result of a combination of the kinetic theory of an ideal gas and the Smoluchowski theory with Fuchs' correction, considering the interaction between identical spherical particles and their surfaces immersed in a symmetrical electrolyte solution. The agreement with experimental data suggested that it is superior to the classical ones in describing the weak dependence of the stability ratio on the particle size and the valence of the counterion, by emphasizing the importance of the secondary minimum coagulation in dispersion stability and the complementation between the two modes of coagulation.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2022. Vol. 38, no 3, p. 1131-1140
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-310206DOI: 10.1021/acs.langmuir.1c02790ISI: 000763460000026PubMedID: 35015554Scopus ID: 2-s2.0-85123878443OAI: oai:DiVA.org:kth-310206DiVA, id: diva2:1648333
Note

QC 20220330

Available from: 2022-03-30 Created: 2022-03-30 Last updated: 2022-06-25Bibliographically approved

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Liu, Longcheng

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