The possibility to harvest energy from ambient radio-frequency (RF) sources has intrigued humankind for the past several decades. In this context, there has been a tremendously growing research interest in the field of wireless power transfer (WPT) using the RF range of the electromagnetic (EM) spectrum. In this paper, we experimentally investigate the aspect of real-time energy harvesting (EH) via different types of waveform designs such as orthogonal frequency division multiplexing (OFDM), square, triangular, sinusoidal, and sawtooth. We make use of a Software Defined Radio (SDR) and a Powercast P21XXCSR-EVB EH module to carry out the experiments on a practical device to assess performance. Specifically, we are interested in obtaining some insights based on the comparison between the aforementioned waveform designs from the perspectives of the separation distance between the USRP and P21XXCSR-EVB EH module, and power emission via USRP. In this vein, we perform additional subsequent experiments after reporting the practical effectiveness of the OFDM waveform, which also follows our intuitive analysis. Correspondingly, we study the effect on WPT with variable USRP transmit power, the separation distance between the USRP and EH antennas, number of OFDM sub-carriers, and multipath setting. As an application of OFDM, the effectiveness of fifth generation-new radio (5G-NR) and long-term evolution (LTE) waveforms are also tested for the WPT mechanism. The demonstration of the EH is provided in terms of the above-mentioned investigation metrics while seeking the best waveform to support WPT.