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Revisiting the applications of the extraction replica sample preparation technique for analysis of precipitates in engineering alloys
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Properties.
Swerim AB, Isafjordsgatan 28A, SE-16407 Kista, Sweden..
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Properties.ORCID iD: 0000-0003-1102-4342
2022 (English)In: Materials Characterization, ISSN 1044-5803, E-ISSN 1873-4189, Vol. 189, p. 111978-, article id 111978Article in journal (Refereed) Published
Abstract [en]

The extraction replica technique is a useful sample preparation method to fabricate transmission electron microscopy samples for subsequent studies of small particles, such as precipitates, in different types of alloys. With other sample preparation methods, such as thin foil fabrication, the surrounding matrix might influence compositional or crystallographic analysis in the TEM. The extraction replica technique omits that problem, as the precipitates are extracted onto a thin, amorphous film (most commonly carbon) and the influence of the matrix is thus eliminated. The replica can be produced in a direct manner, by a two stage-method or in certain cases by the oxide replica method. A variety of precipitates from common engineering alloys including carbides, nitrides, oxides and various intermetallic phases in steels, nickel-, zirconium-, aluminium-, copper-, and magnesium-based alloys, can be extracted and the techniques are summarized in this work. The choice of etchant is crucial for the end result, as is also showcased experimentally in this work. Furthermore, the direct replica and two-stage replica method are directly compared with each other by new experiments on a low alloyed steel and a zirconium alloy. There are indications that the direct method has a greater particle extraction efficiency of smaller particles compared to the two-stage method. Moreover, the direct method also facilitates the analysis of other features, such as grain boundaries, in special cases.

Place, publisher, year, edition, pages
Elsevier BV , 2022. Vol. 189, p. 111978-, article id 111978
Keywords [en]
Extraction replica, TEM, Precipitates
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:kth:diva-315548DOI: 10.1016/j.matchar.2022.111978ISI: 000806861900003Scopus ID: 2-s2.0-85130477906OAI: oai:DiVA.org:kth-315548DiVA, id: diva2:1682030
Note

QC 20220708

Available from: 2022-07-08 Created: 2022-07-08 Last updated: 2023-12-07Bibliographically approved

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Rolinska, MonikaHedström, Peter

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