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Crystal structure of the sodium salt of the uranyl-oxyacetate-fluoride dimer, Na4(UO2)2(OCH2COO)2F 4 · 6H2O
KTH, Superseded Departments (pre-2005), Chemistry.ORCID iD: 0000-0002-7552-1076
1999 (English)In: Acta Chemica Scandinavica, ISSN 0904-213X, E-ISSN 1902-3103, Vol. 53, no 11, p. 1009-1012Article in journal (Refereed) Published
Abstract [en]

The structure of the ternary uranyl-oxyacetate-fluoride dimer, (UO2)2(OCH2COO)2F4 4-, was studied by single crystal X-ray diffraction. The space group is P1̄, and the structure contains discrete dimers with a double pentagonal bipyramid geometry, linked by octahedrally coordinated sodium ions. The uranyl ion has a coordination number of five with two fluorides and three oxygens coordinated in a plane perpendicular to the linear UO2 axis. The dimer is formed via bridging oxygen atoms from the deprotonated hydroxyl groups of the glycolate ligands.

Place, publisher, year, edition, pages
Danish Chemical Society , 1999. Vol. 53, no 11, p. 1009-1012
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-317898DOI: 10.3891/acta.chem.scand.53-1009ISI: 000083445200009Scopus ID: 2-s2.0-0346335953OAI: oai:DiVA.org:kth-317898DiVA, id: diva2:1695824
Note

QC 20220915

Available from: 2022-09-14 Created: 2022-09-14 Last updated: 2022-09-15Bibliographically approved

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Szabó, Zoltan

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