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n-Type Organic Electrochemical Transistors with High Transconductance and Stability
Guangzhou Key Laboratory of Flexible Electronic Materials and Wearable Devices School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, People's Republic of China.
Guangzhou Key Laboratory of Flexible Electronic Materials and Wearable Devices School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510275, People's Republic of China.
KTH, Centres, Science for Life Laboratory, SciLifeLab. KTH, Centres, Center for the Advancement of Integrated Medical and Engineering Sciences, AIMES. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Protein Science, Nano Biotechnology. Department of Neuroscience, Karolinska Institute, Stockholm 17177, Sweden. (CBH Digital Futures)ORCID iD: 0000-0002-6428-0633
Biological and Environmental Science and Engineering (BESE) Organic Bioelectronics Laboratory, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.
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2023 (English)In: Chemistry of Materials, ISSN 0897-4756, E-ISSN 1520-5002, Vol. 35, no 2, p. 405-415Article in journal (Refereed) Published
Abstract [en]

An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2023. Vol. 35, no 2, p. 405-415
National Category
Condensed Matter Physics Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-335755DOI: 10.1021/acs.chemmater.2c02447ISI: 000923050400001Scopus ID: 2-s2.0-85146133468OAI: oai:DiVA.org:kth-335755DiVA, id: diva2:1795829
Note

QC 20230911

Available from: 2023-09-11 Created: 2023-09-11 Last updated: 2023-09-11Bibliographically approved

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Zeglio, EricaHerland, Anna

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