n-Type Organic Electrochemical Transistors with High Transconductance and StabilityShow others and affiliations
2023 (English)In: Chemistry of Materials, ISSN 0897-4756, E-ISSN 1520-5002, Vol. 35, no 2, p. 405-415Article in journal (Refereed) Published
Abstract [en]
An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.
Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2023. Vol. 35, no 2, p. 405-415
National Category
Condensed Matter Physics Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-335755DOI: 10.1021/acs.chemmater.2c02447ISI: 000923050400001Scopus ID: 2-s2.0-85146133468OAI: oai:DiVA.org:kth-335755DiVA, id: diva2:1795829
Note
QC 20230911
2023-09-112023-09-112023-09-11Bibliographically approved