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Nonlocal resonant inelastic x-ray scattering
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Theoretical Chemistry and Biology. International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia.ORCID iD: 0000-0003-3072-3173
School of Mathematics and Physics, North China Electric Power University, 102206 Beijing, China; Hebei Key Laboratory of Physics and Energy Technology, North China Electric Power University, 071000 Baoding, China.
International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia.
International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia.
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2023 (English)In: Physical Review A: covering atomic, molecular, and optical physics and quantum information, ISSN 2469-9926, E-ISSN 2469-9934, Vol. 108, no 5, article id 052820Article in journal (Refereed) Published
Abstract [en]

In the description of resonant inelastic x-ray scattering (RIXS) from inversion-symmetric molecules the small core-level splitting is typically neglected. However, the spacing Δ between gerade and ungerade core levels in homonuclear diatomic molecules can be comparable with the lifetime broadening of the intermediate core-excited state Γ. We show that when Δ∼Γ the scattering becomes nonlocal in the sense that x-ray absorption at one atomic site is followed by emission at the other one. This is manifested in an unusual dependence of the RIXS cross section on the sum of the momenta of incoming and outgoing x-ray photons k+k′, contrary to the normal k-k′ dependence in the conventional local RIXS theory. The nonlocality of the scattering influences strongly the scattering angle and excitation energy dependence of the intensity ratio between parity forbidden and allowed RIXS channels. Numerical simulations for N2 show that this effect can readily be measured at present-day x-ray radiation facilities.

Place, publisher, year, edition, pages
American Physical Society (APS) , 2023. Vol. 108, no 5, article id 052820
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Atom and Molecular Physics and Optics Theoretical Chemistry
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URN: urn:nbn:se:kth:diva-340968DOI: 10.1103/PhysRevA.108.052820ISI: 001110269800001Scopus ID: 2-s2.0-85178134973OAI: oai:DiVA.org:kth-340968DiVA, id: diva2:1820281
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QC 20231218

Available from: 2023-12-18 Created: 2023-12-18 Last updated: 2024-02-29Bibliographically approved

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Gel'mukhanov, FarisKimberg, Victor

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