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X-ray-Induced Molecular Catapult: Ultrafast Dynamics Driven by Lightweight Linkages
Sorbonne Univ, CNRS, UMR 7614, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France..ORCID iD: 0000-0001-9504-3692
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Theoretical Chemistry and Biology.ORCID iD: 0000-0003-1269-8760
Sorbonne Univ, CNRS, UMR 7614, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France..
Gesellschaft, Fritz Haber Inst Max Planck, Mol Phys, D-14195 Berlin, Germany..ORCID iD: 0000-0002-0891-9180
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2024 (English)In: The Journal of Physical Chemistry Letters, E-ISSN 1948-7185, Vol. 15, no 47, p. 11883-11890Article in journal (Refereed) Published
Abstract [en]

In our work, we demonstrate that X-ray photons can initiate a "molecular catapult" effect, leading to the dissociation of chemical bonds and the formation of heavy fragments within just a few femtoseconds. We reconstruct the momenta of fragments from a three-body dissociation in bromochloromethane using the ion pair average (IPA) reference frame, demonstrating how light atomic groups, such as alkylene and alkanylene, can govern nuclear dynamics during the dissociation process, akin to projectiles released by a catapult. Supported by ab initio calculations, this work highlights the crucial role of low-reduced-mass vibrational modes in driving ultrafast chemical processes.

Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2024. Vol. 15, no 47, p. 11883-11890
National Category
Atom and Molecular Physics and Optics
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URN: urn:nbn:se:kth:diva-357567DOI: 10.1021/acs.jpclett.4c02511ISI: 001360666300001PubMedID: 39569981Scopus ID: 2-s2.0-85210086075OAI: oai:DiVA.org:kth-357567DiVA, id: diva2:1919415
Note

QC 20241209

Available from: 2024-12-09 Created: 2024-12-09 Last updated: 2024-12-09Bibliographically approved

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Kimberg, Victor

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