kth.sePublications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Nucleation Kinetics of Freeze Crystallization with Various Aqueous Solutions
Aalto University Department of Chemical and Metallurgical Engineering P.O. Box 16100 FI-00076 Aalto Finland.ORCID iD: 0000-0003-1967-514X
Aalto University Department of Chemical and Metallurgical Engineering P.O. Box 16100 FI-00076 Aalto Finland.ORCID iD: 0000-0002-0987-1406
2023 (English)In: Chemical Engineering & Technology, ISSN 0930-7516, E-ISSN 1521-4125, Vol. 46, no 11, p. 2316-2320Article in journal (Refereed) Published
Abstract [en]

The nucleation kinetics of ice were investigated with four different types of aqueous solutions. The studied aqueous solutions, i.e., sucrose solution, ionic liquid (IL) solution, pyrolysis oil extract (PO) solution, and acetone‐1‐butanol‐ethanol (ABE) solution, were concentrated by batch suspension freeze crystallization. The nucleation kinetics were investigated using a temperature response method which results in data on nucleation rate per crystal. The obtained nucleation rate per crystal value can be used when dimensioning continuous crystallization processes: the nucleation rate per crystal is inversely proportional to the residence time in continuous crystallization. The subcooling degrees for different solutions were in the range of 0.33 °C to 1.89 °C. Aqueous sucrose solutions had the fastest nucleation kinetics. Ice crystallization from non‐ideal aqueous [DBNH][OAc] ionic liquid solutions required higher subcooling degrees and the nucleation rates per crystal were higher as well. Nucleation of ice formed from aqueous pyrolysis oil extract and aqueous ABE solutions occurred at a lower subcooling degree and the obtained nucleation rate per crystal values were lower.

Place, publisher, year, edition, pages
Wiley , 2023. Vol. 46, no 11, p. 2316-2320
National Category
Separation Processes
Identifiers
URN: urn:nbn:se:kth:diva-362860DOI: 10.1002/ceat.202300072ISI: 001085508600001Scopus ID: 2-s2.0-85174007286OAI: oai:DiVA.org:kth-362860DiVA, id: diva2:1954998
Note

QC 20250428

Available from: 2025-04-28 Created: 2025-04-28 Last updated: 2025-04-28Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Osmanbegovic, Nahla

Search in DiVA

By author/editor
Osmanbegovic, NahlaLouhi-Kultanen, Marjatta
In the same journal
Chemical Engineering & Technology
Separation Processes

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 12 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf