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High-temperature Mass Spectrometric Study of the Vaporization of Dysprosium Trifluoride
KTH, Superseded Departments, Metallurgy.
KTH.
1996 (English)In: Rapid Communications in Mass Spectrometry, ISSN 0951-4198, E-ISSN 1097-0231, Vol. 10, no 5, 501-508 p.Article in journal (Refereed) Published
Abstract [en]

The high-temperature Knudsen effusion method was used to study the vaporization processes and thermodynamic properties of dysprosium trifluoride in the temperature range 1280-1440 K. Data on the partial vapour pressure of DyF3 as a function of temperature and the enthalpy of sublimation of DyF3 were obtained. Using the value of the enthalpy of formation of solid DyF3, available in the literature, the enthalpy of formation of the gaseous molecule of dysprosium trifluoride and its atomization energy were calculated. At 1382 K, the partial vapour pressure of Dy2F6 over dysprosium trifluoride was obtained and the Gibbs energy of the gaseous reaction (Dy2F6)=(2DyF3) was evaluated.

Place, publisher, year, edition, pages
1996. Vol. 10, no 5, 501-508 p.
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:kth:diva-12277DOI: 10.1002/(SICI)1097-0231(19960331)10:5<501::AID-RCM503>3.0.CO;2-YOAI: oai:DiVA.org:kth-12277DiVA: diva2:307589
Note
QC 20100401Available from: 2010-04-01 Created: 2010-04-01 Last updated: 2017-12-12Bibliographically approved
In thesis
1. Thermodynamic studies of some high temperature systems
Open this publication in new window or tab >>Thermodynamic studies of some high temperature systems
1997 (English)Doctoral thesis, comprehensive summary (Other scientific)
Place, publisher, year, edition, pages
Stockholm: Institutionen för tillämpad processmetallurgi, 1997. 162 p.
Series
Trita-MET, 97:187
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-2593 (URN)91-7170-202-4 (ISBN)
Public defence
1997-12-05, 00:00 (English)
Note
QC 2010-05-04Available from: 2000-01-01 Created: 2000-01-01 Last updated: 2010-05-04Bibliographically approved

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