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Wood-fibre composites: Stress transfer and hygroexpansion
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
2010 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Wood fibres is a type of natural fibres suitable for composite applications. The abundance of wood in Swedish forests makes wood-fibre composites a new and interesting application for the Swedish pulp and paper industry. For large scale production of composites reinforced by wood fibres to be realized, the mechanical properties of the materials have to be optimized. Furthermore, the negative effects of moisture, such as softening, creep and degradation, have to be limited. A better understanding of how design parameters such as choice of fibres and matrix material, fibre modifications and fibre orientation distribution affect the properties of the resulting composite material would help the development of wood-fibre composites.

In this thesis, focus has been on the fibre-matrix interface, wood-fibre hygroexpansion and resulting mechanical properties of the composite. The importance of an efficient fibre-matrix interface for composite properties is well known, but the determination of interface properties in wood-fibre composites is difficult due to the miniscule dimensions of the fibres. This is a problem also when hygroexpansion of wood fibres is investigated. Instead of tedious single-fibre tests, more straightforward, macroscopic approaches are suggested. Halpin-Tsai’s micromechanical models and laminate analogy were used to attain efficient interface characteristics of a wood-fibre composite. When Halpin-Tsai’s model was replaced by Hashin’s concentric cylinder assembly model, a value of an interface parameter could be derived from dynamic mechanical analysis. A micromechanical model developed by Hashin was used also to identify the coefficient of hygroexpansion of wood fibres. Measurements of thickness swelling of wood-fibre composites were performed. Back-calculation through laminate analogy and the micromechanical model made it possible to estimate the wood-fibre coefficient of hygroexpansion. Through these back-calculation procedures, information of fibre and interface properties can be gained for ranking of e.g. fibre types and modifications.

Dynamic FT-IR (Fourier Transform Infrared) spectroscopy was investigated as a tool for interface characterization at the molecular level. The effects of relative humidity in the test chamber on the IR spectra were studied. The elastic response of the matrix material increased relative to the motion of the reinforcing cellulose backbone. This could be understood as a stress transfer from fibres to matrix when moisture was introduced to the system, e.g. as a consequence of reduced interface efficiency in the moist environment. The method is still qualitative and further development is potentially very useful to measure stress redistribution on the molecular level.

Place, publisher, year, edition, pages
Stockholm: KTH , 2010. , 51 p.
Series
Trita-CHE-Report, ISSN 1654-1081 ; 2010:9
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:kth:diva-12309OAI: oai:DiVA.org:kth-12309DiVA: diva2:309582
Public defence
2010-04-16, K1, Teknikringen 56 entrépla, KTH, Stockholm, 10:00 (English)
Opponent
Supervisors
Note
QC20100714Available from: 2010-04-07 Created: 2010-04-07 Last updated: 2010-11-02Bibliographically approved
List of papers
1. Dynamic-mechanical properties of wood-fibre reinforced polyactide: experimental characterization and micro-mechanical modelling
Open this publication in new window or tab >>Dynamic-mechanical properties of wood-fibre reinforced polyactide: experimental characterization and micro-mechanical modelling
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2006 (English)In: Journal of Thermoplastic Composite Materials, ISSN 0892-7057, E-ISSN 1530-7980, Vol. 19, no 6, 613-638 p.Article in journal (Refereed) Published
Abstract [en]

Wood-fiber reinforced polylactide is a biodegradable compositewhere both fibers and matrix are from renewableresources. When designing new materials of this kind, itis useful to measure the influence of fiber–matrixinterface properties on macroscopic mechanicalproperties. In particular, a quantitative measure of thedynamic stress transfer between the fibers andthe matrix when the material is subjected tocyclic loading would simplify the development of wood-fibercomposites. This is obtained by comparing themechanical dissipation of the composite with avalue predicted by a viscoelastic micromechanical model basedon perfect interfacial stress transfer. Theloss factors predicted by the model are 0.12 and 0.16 at dryand humid conditions, respectively, which amountto 63 and 66% of the experimentally determinedvalues. For Young's moduli the predicted values are 1.01 and0.88 GPa, which correspond to 92% of the experimentallydetermined values. The mismatch between thepredicted and experimental values may be attributed toimperfect interfaces with restrained stress transfer.Loss factors are also determined for specificmolecular bonds using dynamic Fourier transform infrared(FT-IR) spectroscopy. These values show the sametrends with regard to moisture content as themacroscopically determined loss factors.

Keyword
polylactide • wood fibers • micromechanics • stress transfer • imperfect interfaces • dynamic FT–IR
National Category
Mechanical Engineering
Identifiers
urn:nbn:se:kth:diva-6991 (URN)10.1177/0892705706067480 (DOI)000241384300001 ()2-s2.0-33750180040 (Scopus ID)
Note
QC 20100714Available from: 2007-04-19 Created: 2007-04-19 Last updated: 2017-12-14Bibliographically approved
2. Effects of Moisture on Dynamic Mechanical Properties of Wood Fiber Composites Studied by Dynamic FT-IR Spectroscopy
Open this publication in new window or tab >>Effects of Moisture on Dynamic Mechanical Properties of Wood Fiber Composites Studied by Dynamic FT-IR Spectroscopy
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2008 (English)In: Journal of reinforced plastics and composites (Print), ISSN 0731-6844, E-ISSN 1530-7964, Vol. 27, no 16-17, 1709-1721 p.Article in journal (Refereed) Published
Abstract [en]

Wood fiber reinforced polylactide is a biodegradable composite where both fibers and matrix are from renewable resources. In the development of such new materials, information on mechanical behavior on the macroscopic and the molecular level is useful. In this study, dynamic Fourier transform infrared (FT-IR) spectroscopy is used to measure losses at the molecular level during cyclic tensile loading for bonds that are characteristic of the cellulosic fibers and the polylactid matrix. This molecular behavior is compared with measured macroscopic hysteresis losses for different moisture levels. The results show that moisture ingress will transfer the load from the fibers to the matrix, and that a more efficient fiber-matrix interface would diminish mechanical losses. Although the dynamic FT-IR spectroscopy method is still qualitative, this investigation shows that it can provide information on the stress transfer of the constituents in wood fiber reinforced plastics.

Keyword
wood fiber, dynamic FT-IR, stress transfer, moisture, interface
National Category
Paper, Pulp and Fiber Technology Mechanical Engineering
Identifiers
urn:nbn:se:kth:diva-6992 (URN)10.1177/0731684407084663 (DOI)000260411900005 ()
Note
QC20100714. Tidigare titel "Effects of moisture on dynamic mechanical properties of wood-fibre reinforced polylactide studied by dynamic FT-IR spectroscopy. Available from: 2007-04-19 Created: 2007-04-19 Last updated: 2017-12-14Bibliographically approved
3. Characterization of interfacial stress transfer ability by dynamic mechanical analysis of cellulose fiber based composite materials
Open this publication in new window or tab >>Characterization of interfacial stress transfer ability by dynamic mechanical analysis of cellulose fiber based composite materials
2010 (English)In: Composite interfaces (Print), ISSN 0927-6440, E-ISSN 1568-5543, Vol. 17, no 9, 845-861 p.Article in journal (Refereed) Published
Abstract [en]

The stress transfer ability at the fiber-matrix interface of wood fiber composites is known to affect the mechanical properties of the composite. The evaluation of interface properties at the level of individual fibers is however difficult due to the small dimensions and variability of the fibers. The dynamical mechanical properties of composite and constituents, in this case wood fibers and polylactide matrix, was here used together with micromechanical modeling to quantify the stress transfer efficiency at the fiber-matrix interface. To illustrate the methodology, a parameter quantifying the degree of imperfection at the interface was identified by inverse modeling using a micromechanical viscoelastic general self-consistent model with an imperfect interface together with laminate analogy on the composite level. The effect of moisture was assessed by comparison with experimental data from dynamic mechanical analysis in dry and moist state. For the wood fiber reinforced polylactide, the model shows that moisture absorption led to softening and mechanical dissipation in the hydrophilic wood fibers and biothermoplastic matrix, rather than loss of interfacial stress transfer ability.

Keyword
Wood fibers, micromechanics, imperfect interface, inverse modeling, moisture
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-12285 (URN)10.1163/092764410X539235 (DOI)000289243400003 ()2-s2.0-78649519331 (Scopus ID)
Available from: 2010-04-01 Created: 2010-04-01 Last updated: 2017-12-12Bibliographically approved
4. Role of fibre-fibre and fibre-matrix adhesion in stress transfer in composites made from resin-impregnated paper sheets.
Open this publication in new window or tab >>Role of fibre-fibre and fibre-matrix adhesion in stress transfer in composites made from resin-impregnated paper sheets.
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2009 (English)In: International Journal of Adhesion and Adhesives, ISSN 0143-7496, E-ISSN 1879-0127, Vol. 29, no 5, 551-557 p.Article in journal (Refereed) Published
Abstract [en]

Paper-reinforced plastics are gaining increased interest as packaging materials, where mechanical properties are of great importance. Strength and stress transfer in paper sheets are controlled by fibre-fibre bonds. In paper-reinforced plastics, where the sheet is impregnated with a polymer resin, other stress-transfer mechanisms may be more important. The influence of fibre-fibre bonds on the strength of paper-reinforced plastics was therefore investigated. Paper sheets with different degrees of fibre-fibre bonding were manufactured and used as reinforcement in a polymeric matrix. Image analysis tools were used to verify that the difference in the degree of fibre-fibre bonding had been preserved in the composite materials. Strength and stiffness of the composites were experimentally determined and showed no correlation to the degree of fibre-fibre bonding, in contrast to the behaviour of unimpregnated paper sheets. The degree of fibre-fibre bonding is therefore believed to have little importance in this type of material, where stress is mainly transferred through the fibre-matrix interface.

Keyword
Composites, Wood, Microscopy
National Category
Mechanical Engineering Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-6993 (URN)10.1016/j.ijadhadh.2008.11.002 (DOI)000265185300011 ()2-s2.0-62249147592 (Scopus ID)
Note
Tidigare titel: Comparison of stress-transfer mechanisms in paper sheets and composites med from resin-impregnated sheets. Uppdaterad från submitted till published: 20101102. QC 20101102Available from: 2007-04-19 Created: 2007-04-19 Last updated: 2017-12-14Bibliographically approved
5. Moisture uptake and hygroexpansion of wood fiber composite materials with polylactide and polypropylene matrix materials
Open this publication in new window or tab >>Moisture uptake and hygroexpansion of wood fiber composite materials with polylactide and polypropylene matrix materials
2009 (English)In: Polymer Composites, ISSN 0272-8397, E-ISSN 1548-0569, Vol. 30, no 12, 1809-1816 p.Article in journal (Refereed) Published
Abstract [en]

Effects of butantetracarboxylic acid (BTCA) modification, choice of matrix, and fiber volume fraction on hygroexpansion of wood fiber composites have been investigated. Untreated reference wood fibers and BTCA-modified fibers were used as reinforcement in composites with matrices composed of polylactic acid (PLA), polypropylene (PP), or a mixture thereof. The crosslinking BTCA modification reduced the out-of-plane hygroexpansion of PLA and PLA/PP composites, under water-immersed and humid conditions, whereas the swelling increased when PP was used as matrix material. This is explained by difficulties for the BTCA-modified fibers to adhere to the PP matrix. Fiber volume fraction was the most important parameter as regards out-of-plane hygroexpansion, with a high-fiber fraction leading to large hygroexpansion. Fiber-matrix wettability during processing and consolidation also showed to have a large impact on the dimensional stability and moisture uptake. POLYM. COMPOS., 30:1809-1816, 2009.

Keyword
DIMENSIONAL STABILITY; MECHANICAL-PROPERTIES; ABSORPTION; POLYMER; DEGRADATION; WATER; ACID
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-12288 (URN)10.1002/pc.20753 (DOI)000272284900010 ()2-s2.0-73249147817 (Scopus ID)
Note
QC 20100617Available from: 2010-04-01 Created: 2010-04-01 Last updated: 2017-12-12Bibliographically approved
6. Contribution of wood fiber hygroexpansion to moisture induced thickness swelling of composite plates
Open this publication in new window or tab >>Contribution of wood fiber hygroexpansion to moisture induced thickness swelling of composite plates
2010 (English)In: Polymer Composites, ISSN 0272-8397, E-ISSN 1548-0569, Vol. 31, no 5, 762-771 p.Article in journal (Refereed) Published
Abstract [en]

One of the main drawbacks of wood fiber-based composite materials is their propensity to swell due to moisture uptake. Because the wood fibers are usually the main contributor to hygroexpansion, it is of interest to quantify the hygroexpansion coefficient of wood fibers, to compare and rank different types of fibers. This investigation outlines an inverse method to estimate the transverse hygroexpansion coefficient of wood fibers based on measurements of moisture induced thickness swelling of composite plates. The model is based on composite micromechanics and laminate theory. Thickness swelling has been measured on polylactide matrix composites with either bleached reference fibers or crosslinked fibers. The crosslinking modification reduced the transverse hygroexpansion of the composites and the transverse coefficient of hygroexpansion of the fibers was reduced from 0.28 strain per relative humidity for reference fibers to 0.12 for cross-linked fibers

Keyword
Crosslinked, Hygroexpansion, Inverse methods, Laminate theory, Matrix composite, Moisture uptake, Poly lactide, Reference fibers, Relative humidities, Thickness swelling, Wood fiber
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:kth:diva-12289 (URN)10.1002/pc.20858 (DOI)000277056200002 ()2-s2.0-77951797297 (Scopus ID)
Note
QC 20100714Available from: 2010-04-01 Created: 2010-04-01 Last updated: 2017-12-12Bibliographically approved

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Citation style
  • apa
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  • ieee
  • modern-language-association-8th-edition
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