Dynamical suppression of atomic peaks in resonant dissociative photoemission
2001 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 343, no 3-4, 332-338 p.Article in journal (Refereed) Published
Resonant excitation to the F1s-sigma* dissociative state in hydrogen fluoride gives a photoelectron spectrum where the spectator part contains strong atomic lines but a participator part where such lines are lacking. We demonstrate that this contrasting behaviour between the two parts is due to a strong dynamical suppression of the resonant contribution, making direct main state photoionization the dominating channel even at resonant conditions.
Place, publisher, year, edition, pages
2001. Vol. 343, no 3-4, 332-338 p.
ray raman-scattering, molecules, spectra, hcl, excitation, states, decay
Atom and Molecular Physics and Optics Physical Chemistry
IdentifiersURN: urn:nbn:se:kth:diva-13836DOI: 10.1016/S0009-2614(01)00667-4ISI: 000170235700021OAI: oai:DiVA.org:kth-13836DiVA: diva2:327694
QC 201006302010-06-302010-06-302012-06-12Bibliographically approved