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Correlation and prediction of activity and osmotic coefficients of aqueous electrolytes at 298.15 K by the modified TCPC model
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Materials Process Science.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Materials Process Science.
2007 (English)In: Journal of Chemical and Engineering Data, ISSN 0021-9568, E-ISSN 1520-5134, Vol. 52, no 2, 538-547 p.Article in journal (Refereed) Published
Abstract [en]

The modification and extension of a three-characteristic-parameter correlation model for calculating the thermodynamic properties including osmotic and mean activity coefficients of aqueous electrolytes at 298.15 K have been presented in this paper. The model can be reduced with two parameters: b, the approaching parameter, and S, the solvation parameter. Although the model adequately describes the thermodynamics with these two parameters, the third parameter, n, which is related to the distance between an ion and a solvent molecule, also can be regarded as an adjustable parameter. The two sets of parameters for 283 single salts in aqueous solutions up to saturation have been obtained from the regression of experimental values. Mean activity or osmotic coefficients of RbNO2, MgCl2, Sm(ClO4)(3), and ZnSO4, with these two sets of parameters, have been compared with the smoothed experimental data, which show good agreement. When the model with three parameters is employed, it gives a more accurate result, especially in case of high concentration. The comparison with Pitzer and the original TCPC model also illustrates the excellent performance of this modified model.

Place, publisher, year, edition, pages
2007. Vol. 52, no 2, 538-547 p.
Keyword [en]
VAPOR-LIQUID-EQUILIBRIA; BI-UNIVALENT COMPOUNDS; 3-CHARACTERISTIC-PARAMETER CORRELATION MODEL; ION INTERACTION PARAMETERS; RARE-EARTH PERCHLORATES; LOCAL COMPOSITION MODEL; EXCESS GIBBS ENERGY; ISOPIESTIC DETERMINATION; THERMODYNAMIC PROPERTIES; EVALUATED ACTIVITY
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-14112DOI: 10.1021/je060451kISI: 000244734600036Scopus ID: 2-s2.0-33947610111OAI: oai:DiVA.org:kth-14112DiVA: diva2:329875
Note
QC 20100714Available from: 2010-07-14 Created: 2010-07-14 Last updated: 2010-07-15Bibliographically approved
In thesis
1. Extraction of Metal Values: Thermodynamics of Electrolyte Solutions and Molten Salts Extraction Process
Open this publication in new window or tab >>Extraction of Metal Values: Thermodynamics of Electrolyte Solutions and Molten Salts Extraction Process
2009 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Over the past centuries, a number of process routes for extraction of metal values from an ore or other resources have been developed. These can generally be classifiedinto pyrometallurgical, hydrometallurgical or electrometallurgical routes. In the caseof the latter two processes, the reaction medium consists of liquid phase electrolytesthat can be aqueous, non-aqueous as well as molten salts. The present dissertationpresents the work carried out with two aspects of the above-mentioned electrolytes.First part is about the electrolyte solutions, which can be used in solvent extractionrelevant to many hydrometallurgical or chemical engineering processes; the secondpart is about the molten salts, which is often used in the electrometallurgical processesfor production of a variety of many kinds of metals or alloys, especially those that arehighly reactive.In the first part of this thesis, the focus is given to the thermodynamics ofelectrolyte solutions. Since the non-ideality of high concentration solution is not wellsolved, a modified three-characteristic-parameter correlation model is proposed,which can calculate the thermodynamic properties of high concentration electrolytesolutions accurately. Model parameters for hundreds of systems are obtained foraqueous as well as non-aqueous solutions. Moreover, a new predictive method tocalculate the freezing point depression, boiling point elevation and vaporizationenthalpy of electrolyte solutions is also proposed. This method has been shown to be agood first approximation for the prediction of these properties.In the second part, a process towards the extraction of metal values from slags,low-grade ores and other oxidic materials such as spent refractories using molten saltsis presented. Firstly, this process is developed for the recovery of Cr, Fe values fromEAF slag as well as chromite ore by using NaCl-KCl salt mixtures in the laboratoryscale. The slags were allowed to react with molten salt mixtures. This extraction stepwas found to be very encouraging in the case of Cr and Fe present in the slags. Byelectrolysis of the molten salt phase, Fe-Cr alloy was found to be deposited on thecathode surface. The method is expected to be applicable even in the case of V, Mnand Mo in the waste slags.Secondly, this process was extended to the extraction of copper/iron from copperore including oxidic and sulfide ores under controlled oxygen partial pressures.Copper or Cu/Fe mixtures could be found on the cathode surface along with theemission of elemental sulphur that was condensed in the cooler regions of the reactor.Thus, the new process offers a potential environmentally friendly process routereducing SO2 emissions.Furthermore, the cyclic voltammetric studies of metal ions(Cr, Fe, Cu, Mg, Mn)in (CaCl2-)NaCl-KCl salt melt were performed to understand the mechanisms, such asthe deposition potential, electrode reactions and diffusion coefficients, etc. In addition,another method using a direct electro-deoxidation concept(FFC Cambridge method),was also investigated for the electrolysis of copper sulfide. Sintered solid porouspellets of copper sulfide Cu2S and Cu2S/FeS were electrolyzed to elemental Cu, S andCu, Fe, S respectively in molten CaCl2-NaCl at 800oC under the protection of Argongas. This direct electrolysis of the sulfide to copper with the emission of elementalsulfur also offers an attractive green process route for the treatment of copper ore.

Place, publisher, year, edition, pages
Stockholm: KTH, 2009. viii, 77 p.
Series
ISRN KTH/MSE, 2009 : 21
Keyword
Electrolyte solutions, activity coefficient, osmotic coefficient, freezing point depression, boiling point elevation
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-10638 (URN)978-91-7415-346-0 (ISBN)
Public defence
2009-06-12, Salongen KTHB, Osquars Backe 31, KTH, Stockholm, 10:00 (English)
Opponent
Supervisors
Note
QC 20100714Available from: 2009-06-09 Created: 2009-06-08 Last updated: 2010-07-15Bibliographically approved

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