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Synthesis and characterization of two novel high valent dinuclear complexes with a triphenolate ligand bearing functional groups
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2005 (English)In: Chinese Chemical Letters, ISSN 1001-8417, Vol. 16, no 1, 89-92 p.Article in journal (Refereed) Published
Abstract [en]

Two novel high valent complexes [M-2(III, III)L(mu-OAc)(2)](PF6)-P-. (M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tertbutyl benzyl)(pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn-2(II, II)(bpmp) (mu-OAc)(2)](CIO4)-C-. (10). These improvements decreased the difference between the new model and (Mn)(4) cluster (OEC in nature).

Place, publisher, year, edition, pages
2005. Vol. 16, no 1, 89-92 p.
Keyword [en]
dinuclear complex, OEC, artificial photosynthesis, phenols
URN: urn:nbn:se:kth:diva-14579ISI: 000227417600026ScopusID: 2-s2.0-33745019365OAI: diva2:332620
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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